Abstract
Magnetic Ascorbic Acid-coated Fe3O4 Nanoparticles were successfully synthesized via a hydrothermal route. The resulting products were characterized by Transmission electron microscope, Fourier transform infrared spectra and X-ray diffraction. Various factors affecting the uptake behavior were discussed, including the pH, adsorption time, adsorbent dosage and initial concentration on the absorption of Cr (VI). Moreover, the thermodynamics and dynamics of the hexavalent chromium ion adsorption were also studied. The results showed that a maximum adsorption capacity was 39.12 mg/g for Cr (VI) at pH 1.50 and the absorption can be up to 85%. The adsorption performance of magnetic nanoparticles in line with both the Langmuir adsorption of Cr (VI) thermodynamic model and HO secondary dynamic adsorption one.
Publication Date
4-28-2017
First Page
75
Last Page
80
DOI
10.13652/j.issn.1003-5788.2017.04.015
Recommended Citation
Jing, YANG and Zhonghai, LI
(2017)
"The Study of Adsorption of Cr(VI) Ions Using Magnetic Ascorbic Acid-coated Fe3O4 Nanoparticles,"
Food and Machinery: Vol. 33:
Iss.
4, Article 15.
DOI: 10.13652/j.issn.1003-5788.2017.04.015
Available at:
https://www.ifoodmm.cn/journal/vol33/iss4/15
References
[1] ZHANG Run-hu, WANG Bo, MA Hong-zhu. Studies on chromium (VI) adsorption on sulfonated lignite[J]. Desalination, 2010, 255(1): 61-66.
[2] SARIN V, PANT K K. Removal of chromium from industrial waste by using eucalyptus bark[J]. Bioresource Technology, 2006, 97(1): 15-20.
[3] 黄丹丹, 孟超, 单宏权, 等. 铬(VI)离子印迹聚合物的研究进展[J]. 天津化工, 2015, 29(5): 5-8.
[4] 张润虎. 磺化褐煤、硫酸掺杂聚苯胺纤维、紫茎泽兰活性炭对六价铬离子的吸附性能研究[D]. 西安: 陕西师范大学, 2012: 3-5.
[5] 单小璇. 磁性纳米材料的化学法制备及性能研究[D]. 广州: 华南理工大学, 2011: 1-4.
[6] 孙海平. 磁性纳米粒子的表面修饰及功能化[D]. 扬州: 扬州大学, 2008: 7-20.
[7] NIU Hong-yun, ZHANG Di, ZHANG Sheng-xiao, et al. Humic acid caoted Fe3O4 magnetic nanoparticles as highly efficient Fenton-like catalyst for complete mineralization of sulfathiazole[J]. Journal of Hazardous Materials, 2011, 190(1/2/3): 559-565.
[8] SHEN Xing-can, FANG Xiu-zhong, ZHOU Ying-hua, et al. Synthesis and Characterization of 3-Aminopropyltriethoxysilane-Modified Superparmagnetic Magnetite Nanopariticles[J]. Chemistry Letters, 2004(11): 1 468-1 469.
[9] 薛君. 功能化磁性纳米材料的制备及其在废水污染物治理中的应用研究[D]. 沈阳: 沈阳理工大学, 2014: 57-58.
[10] MONTAGNE F, MONDAIN-MONVAL O, PICHOT C, et al. Preparation and characterization of narrow sized (o/w) magnetic emulsion[J]. Journal of Magnetism and Magnetic Materials, 2002, 250: 302-312.
[11] LANGMUIR I. The constitution and fundamental properties of solids and liquids. Part II.—Liquids[J]. Journal of the American Chemical Society, 1916, 38(5): 102-105.
[12] 保佳媛, 李俊峰, 张钱丽. 活性炭纤维对亚甲基蓝的吸附动力学和热力学研究[J]. 苏州科技学院学报, 2015, 32(3): 30-35.
[13] AZIZIAN S. Comment on “kinetics of solute adsorption at solid/solution interfaces: a theoretical development of the empirical pseudo-first and pseudo-second order kinetic rate equations, based on applying the statistical rate theory of interfacial transport”[J]. Journal of Physical Chemistry B, 2006, 110(33): 514-525.
[14] AZIZIAN S. Kinetic models of sorption: a theoretical analysis[J]. J Colloid Interface Sci, 2004, 276(1): 47-52.
[15] JOSHI M V. Removal of Cr(VI) and Hg(II) from Aqueous Solutions Using Fly Ash and Impregnated Fly Ash[J]. Separation Science and Technology, 2005, 39(7): 1 611-1 629.
[16] Aydn Y A, Aksoy N D. Adsorption of chromium on chitosan: optimization, kinetics and thermodynamics[J]. Chemical Engineering Journal, 2009, 151(1/2/3): 188-194.
[17] LIU S X, CHEN X, CHEN X Y, et al. Activated carbon with excellent chromium(VI) adsorption performance prepared by acid-base surface modification[J]. Journal of Hazardous Materials, 2007, 141(1): 315-319.
[18] YUAN Peng, FAN Ming-de, YANG Dan, et al. Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions[J]. J. Hazard. Mater., 2009, 166(2/3): 821-829.
[19] HU Jing, CHEN Guohua, LO IMC. Removal and recovery of Cr(VI) from wastewater by maghemite nanoparticles[J]. Water Research, 2005, 39(18): 4 528-4 536.
[20] 赵永纲, 沈昊宇, 李勍, 等. 氨基功能化纳米Fe3O4磁性高分子吸附剂对废水中Cr(VI)的吸附研究[J]. 化学学报, 2009, 67(13): 1 509-1 514.