•  
  •  
 

Abstract

Resistant starches from potato (RS3) were modified by acid hydrolysis combined with heat-moisture treatment (AH-HMT). The effects of changing the starch slurry concentration, the type of acid and its concentration on the structure of RS3 were also studied. The results showed that after AH-HMT, the X-ray pattern remained practically the same with only small changes in the average degree of polymerization (DP), specific surface area (SSA), microstructure (MS), and relative crystallinity (RC). Compared with untreated RS3, the decrease in DP and SSA and the increase in RC caused by high concentrations of acid were significantly greater than those caused by low concentrations of acid. However, the changes in the surface microstructure of RS3 were much more complex. The influence of the five types of organic acid studied on the structural properties of RS3 varied from strong for citric acid, followed by acetic acid, succinic acid, malic acid to weak for lactic acid.

Publication Date

4-28-2017

First Page

9

Last Page

12,32

DOI

10.13652/j.issn.1003-5788.2017.04.002

References

[1] ANN-CHARLOTTE Eliasson. 食品淀粉的结构、功能及应用[M]. 北京: 中国轻工业出版社, 2009: 201-258.
[2] BILIADERIS C G, GRANT D R, VOSE J R. Structural characterization of legume starch. II. Studies on acid-treated starches [J]. Cereal Chemistry, 1981, 58(2): 502-507.
[3] KIM R E, AHN S Y. Gelling properties of acid-modified red bean starch gels [J]. Agric Chem Biotechnol, 1996, 39(1): 49-53.
[4] WANG Ya-janel, TRUONG Van-den, WANG Lin-feng. Structures and rheological properties of corn starch as affected by acid hydrolysis [J]. Carbohydr Polym, 2003, 52(3): 327-333.
[5] NAKAZAWA Yu-ta, WANG Ya-Jane. Acid hydrolysis of native and annealed starches and branch-structure of their Naegeli dextrins [J]. Carbohydr Res, 2003, 338(24): 2 871-2 882.
[6] SHIN S I, BYUN J, PARK K H, et al. Effect of partial acid hydrolysis and heat-moisture treatment on formation of resistant tuber starch [J]. Cereal Chem, 2004, 81(2): 194-198.
[7] CHUNG H J, JEONG H Y, LIM S T. Effects of acid hydrolysis and defatting on crystallinity and pasting properties of freeze-thawed high amylose corn starch [J]. Carbohydr Polym, 2003, 54(4): 449-455.
[8] ADEBOWALE K O, AFOLABI T A, OLU-OWOLABI B I. Hydrothermal treatments of Finger millet (Eleusine coracana) starch [J]. Food Hydrocolloids, 2005, 19(6): 974-983.
[9] GUNARATNE A, HOOVER R. Effect of heat-moisture on the structure and physicochemical properties of tuber and root starches [J]. Carbohydr Polym, 2002, 49(4): 425-437.
[10] 何健, 王韧, 张昊, 等. 改性蜡质玉米淀粉抗消化组分的理化性质及分子结构表征[M]. 食品与机械, 2016, 32(5): 1-4, 10.
[11] HOOVER R, MANUEL H. Theeffect of heat-moisture treatment on the structure and physicochemical properties of normal maize, waxy maize, dull waxy maize and amylomaize V starches [J]. J Cereal Sci, 1996, 23(2): 153-162.
[12] KKSEL H, BASMAN A, KAHRAMAN K, et al. Effect of acid modification and heat treatments on resistant starch formation and functional properties of corn starch [J]. International Journal of Food Properties, 2007, 10(4): 691-702.
[13] KIM W, SHIN M. Effects of organic acids and starch water ratios on the properties of retrograded maize starches [J]. Food Sci Biotechnol, 2011, 20(4): 1 013-1 019.
[14] MUTUNGI C, ONYANGO C, ROST F, et al. Structural and physicochemical properties and in vitro digestibility of recrystallized linear α-D-(1→4) glucans derived from mild-acid modified cassava starch[J]. Food Research International, 2010, 43(4): 1 144-1 154.
[15] SUSHIL D, ASHOK K S, MICHAEL J G. Effect of cryo-milling on starches: functionality and digestibility [J]. Food Hydrocolloids, 2010, 24(2/3): 152-163.
[16] SHIN S I, LEE C J, KIM M J, et al. Structural characteristics of low-glycemic response rice starch produced by citric acid treatment [J]. Carbohydrate Polymers, 2009, 78(3), 588-595.
[17] 谢涛, 曾红华, 汪婕, 等. 4种抗性淀粉的主要理化特性[J]. 中国粮油学报, 2014, 29(9): 78-84.
[18] SUN Qing-jie, ZHU Xiao-lei, SI Fu-mei, et al. Effect of acid hydrolysis combined with heat moisture treatment on structure and physicochemical properties of corn starch [J]. J Food Sci Technol, 2015, 52(1): 375-382.
[19] 谢涛, 张淑远. 重结晶红薯淀粉体外消化前后益生作用与结构变化[J]. 农业机械学报, 2013, 44(8): 203-208.
[20] MUTUNGI C, ONYANGO C, DOERT T, et al. Long- and short-range structural changes of recrystallised cassava starch subjected to in vitro digestion[J]. Food Hydrocolloids, 2011, 25(2): 477-485.
[21] ROBIN F, MERINAT S, SIMON A, et al. Influence of chain length on a-1,4-D-glucan recrystallization and slowly digestible starch formation[J]. Starch/Strke, 2008, 60(10): 551-558.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.