•  
  •  
 

Abstract

In order to reduce phenol in main stream cigarette smoke common-used tobacco flavor (vanillin and citral) were chosen to modify chitosan (CS) via schiff base reaction to prepare vanillin-modified chitosan (CA-Va) and citral-modified chitosan(CS-Ci). The synthesized products were characterized by Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM). The phenol reduction performance of modified chitosan was evaluated with a simulation device. The results showed that: ① When CS-Va was added infive cigarettes, the biggest reducing rate was 28.94%, whereas the biggest reducing rate was 22.04% when CS-Va was added in these five samples; ② The phenol retention increased with the increase of the additive contents; ③ CS-Va had specific milk flavor and CS-Ci had fresh fruit flavor. The research provided new options for reduced-toxicant cigarette material field.

Publication Date

6-28-2017

First Page

164

Last Page

168

DOI

10.13652/j.issn.1003-5788.2017.06.033

References

[1] 王乃定, 向能军, 李春, 等. 不同吸附材料在卷烟降焦减害中的应用[J]. 光谱实验室2010, 27(3): 1 135-1 138.
[2] 霍晓辉, 王玉林, 胡秀峰, 等. 卷烟滤嘴用纤维过滤材料减害降焦效果研究进展[J]. 科技导报, 2007, 25(22): 76-80.
[3] 谢剑平, 刘惠民, 朱茂祥, 等. 卷烟烟气危害性指数研究[J]. 烟草科技, 2009(2): 5-15.
[4] 何景福. 新型材料在卷烟降焦减害中的应用[J], 郑州轻工业学报: 自然科学版, 2007, 22(2): 53-57.
[5] 高明奇, 杨帆, 顾亮, 等. 氧化石墨烯—壳聚糖复合物涂布纸降低卷烟烟气中苯酚和巴豆醛[J]. 烟草科技, 2016, 49(11): 66-73.
[6] 巩文萍, 盛志艺, 陈玉新, 等. 沸石分子筛降低卷烟主流烟气中苯并[a]芘和苯酚的研究[J]. 食品工业科技, 2013, 34(15): 104-111.
[7] 黄富, 金勇, 钟科军, 等. 改性纤维素纸沟槽滤棒选择性降低卷烟烟气中的苯酚[J]. 烟草科技, 2012(7): 54-60.
[8] 童保云, 陈开波, 李村, 等. 金属掺杂多孔氧化物选择性降低卷烟烟气HCN和苯酚研究[J]. 中国烟草学报, 2014, 20(1): 9-14.
[9] 沈玉庆. 壳聚糖及柠檬汁对甘蔗汁保鲜效果的影响[J]. 食品与机械, 2016, 32(5): 122-126.
[10] 于沛沛, 夏文水. 苯甲酸壳聚糖酯的合成及抑菌性能研究[J]. 食品与机械, 2011, 27(5): 115-119.
[11] 韩永萍, 龚平, 李可意. 低聚壳聚糖芳香醛希夫碱中酚羟基的抑菌活性研究[J]. 食品与机械, 2015, 31(1): 127-131.
[12] 任军林, 李小斌, 杜红梅, 等. 壳聚糖在卷烟滤嘴中的应用[J]. 烟草科技, 2005(5): 32-33.
[13] 郭立民, 张谋真. 壳聚糖在卷烟滤嘴中的应用研究[J]. 延安大学学报: 自然科学版, 2000, 19(3): 60-62.
[14] 黄致喜, 徐晓瑾. 烟用香料研究进展简介[J]. 香精香料化妆品, 2003(2): 25-29.
[15] 谢剑平, 宗永立, 屈展, 等. 单体香料在卷烟中作用评价方法的建立及应用[J]. 烟草科技, 2008 (4): 5-13.
[16] WANG Guang, LI Pu-wang, PENG Zheng, et al. Formulation of vanillin cross-linked chitosan nanoparticles and its characterization[J]. Advanced Materials Research, 2011, 335: 474-477.
[17] ZOU Qin, LI Jun-fen, LI Yu-bao. Preparation and characterization of vanillin-crosslinked chitosan therapeutic bioactive microcarriers[J]. International Journal of Biological Macromolecules, 2015, 79: 736-747.
[18] PENG Hai-long, XIONG Hua, LI Jin-hua, et al. Vanillin cross-linked chitosan microspheres for controlled release of resveratrol[J]. Food Chemistry, 2010, 121(1): 23-28.
[19] JIN Xiao-xiao, WANG Jiang-tao, BAI Jie. Synthesis and antimicrobial activity of the schiff base from chitosan and citral[J]. Carbohydrate Research, 2009, 344: 825-829.
[20] 陈新, 邵正中, 黄郁芳, 等. 不同交联剂含量对戊二醛交联壳聚糖膜结构与性能影响的研究[J]. 化学学报, 2000, 58(12): 1 654-1 659.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.