•  
  •  
 

Abstract

Nano-starch has many excellent properties such as rich source, non-toxic, renewable, biodegradable and good biocompatibility, but also has the nano characteristics showing effects of the small and quantum size, surface and interface, and macroscopic quantum tunneling, which was widely used in food industry. The main aim of this review was to introduce preparation and modification methods, and physicochemical properties of nano-starch. Meantime, the application of nano-starch in food industry was also reviewed and prospected.

Publication Date

7-28-2017

First Page

210

Last Page

214,220

DOI

10.13652/j.issn.1003-5788.2017.07.045

References

[1] GALLANT D J, BOUCHET B, BALDWIN P M. Microscopy of starch: evidence of a new level of granule organization[J]. Carbohydrate Polymers, 1997, 32(97): 177-191.
[2] PUTAUX J L, MOLINABOISSEAU S, THOMAS MOMAUR A, et al. Platelet nanocrystals resulting from the disruption of waxy maize starch granules by acid hydrolysis[J]. Biomacromolecules, 2003, 4(5): 1 198-1 202.
[3] 周雨佳, 肖茜, 邓放明. 纳米淀粉的制备及其在可食性薄膜中的应用研究进展[J]. 食品与机械, 2016, 32(9): 229-232.
[4] LI Wen-de, CORKE H, BETA T. Kinetics of hydrolysis and changes in amylose content during preparation of microcryst-alline starch from high-amylose maize starches[J]. Carbohydrate Polymers, 2007, 69(2): 398-405.
[5] DUFRESNE A, JEANYVES C A, HELBERT W. New nanocomposite materials: microcrystalline starch reinforced thermoplastic[J]. Macromolecules, 1996, 29(23): 7 624-7 626.
[6] ANGELLIER H, PUTAUX J L, MOLINA-BOISSEAU S, et al. Starch nanocrystal fillers in an acrylic polymer matrix[J]. Macromolecular Symposia, 2005, 221(1): 95-104.
[7] KIM J Y, PARK D J, LIM S T. Fragmentation of waxy rice starch granules by enzymatic hydrolysis[J]. Cereal Chemistry, 2008, 85(2): 182-187.
[8] LECORRE D, VAHANIAN E, DUFRESNE A, et al. Enzymatic pretreatment for preparing starch nanocrystals[J]. Biomacromolecules, 2012, 13(1): 132-137.
[9] 何健, 王韧, 张昊, 等. 不同修饰程度对蜡质玉米淀粉理化性质和消化特性的影响[J]. 食品与机械, 2016, 32(1): 1-5.
[10] LIU Da-gang, WU Qing-lin, CHEN Hui-huang, et al. Transitional properties of starch colloid with particle size reduction from micro- to nanometer[J]. Journal of Colloid & Interface Science, 2009, 339(1): 117-124.
[11] BEL H S, MAGNIN A, PéTRIER C, et al. Starch nanoparticles formation via high power ultrasonication [J]. Carbohydrate Polymers, 2013, 92(2): 1 625-1 632.
[12] KIM H Y, PARK D J, KIM J Y, et al. Preparation of crystalline starch nanoparticles using cold acid hydrolysis and ultrasonication [J]. Carbohydrate Polymers, 2013, 98(1): 295-301.
[13] 陈启杰, 董徐芳, 周丽玲, 等. 挤压法制备玉米纳米淀粉及其表征[J]. 食品与机械, 2017, 33(5): 40-44.
[14] GIEZEN F E, JONGBOOM R O J, FEIL H, et al. Biopolymer nanoparticles: US, US6677386[P]. 2004-01-13.
[15] SONG D L, THIO Y S, DENG Y. Starch nanoparticle formation via reactive extrusion and related mechanism study[J]. Carbohydrate Polymers, 2011, 85(1): 208-214.
[16] 陈启杰, 晏永祥, 王萍. 一种造纸涂布用纳米淀粉的制备方法: 中国, CN103496151A[P]. 2015-06-17.
[17] ZHOU Gang, LUO Zhi-gang, FU Xiong. Preparation and characterization of starch nanoparticles in ionic liquid-in-oil microemulsions system[J]. Industrial Crops & Products, 2014, 52(1): 105-110.
[18] SHI Ai-ming, LI Dong, WANG Li-jun, et al. Preparation of starch-based nanoparticles through high-pressure homogeni-zation and miniemulsion cross-linking: Influence of various process parameters on particle size and stability[J]. Carbohydrate Polymers, 2011, 83(4): 1 604-1 610.
[19] TAN Ying, XU Kun, LI Ling-lu, et al. Fabrication of size-controlled starch-based nanospheres by nanoprecipitation[J]. Acs Applied Materials & Interfaces, 2009, 1(4): 956-959.
[20] MA Xiao-fei, JIAN Rui-juan, CHANG Peter R, et al. Fabrication and characterization of citric acid-modified starch nanoparticles/plasticized-starch composites[J]. Biomacromolecules, 2008, 9(11): 3 314-3 320.
[21] 孟令儒, 叶小嘉, 吴春森, 等. 直链淀粉链长对蜡质玉米淀粉膜性质的影响[J]. 食品与机械, 2016, 32(6): 19-24, 48.
[22] LECORRE D, BRAS J, DUFRESNE A. Influence of botanic origin and amylose content on the morphology of starch nanocrystals[J]. Journal of Nanoparticle Research, 2011, 13(12): 7 193-7 208.
[23] KIM Hee Young, JU Hun Lee, KIM Jong Yea, et al. Characterization of nanoparticles prepared by acid hydrolysis of various starches[J]. Starch - Strke, 2012, 64(5): 367-373.
[24] WEI Ben-xi, HU Xiu-ting, LI Hong-yan, et al. Effect of pH on dispersity of maize starch nanocrystals in aqueous medium[J]. Food Hydrocolloids, 2014, 36(5): 369-373.
[25] LAMANNA M, MORALES N J, GARCíA N L, et al. Development and characterization of starch nanoparticles by gamma radiation: potential application as starch matrix filler [J]. Carbohydrate Polymers, 2013, 97(1): 90-97.
[26] LIN Ning, HUANG Jin, CHANG Peter R, et al. Preparation, modification, and application of starch nanocrystals in nanomaterials: a review[J]. Journal of Nanomaterials, 2011, 20: 1 687-1 707.
[27] ANGELLIER H, MOLINA-BOISSEAU S, BELGACEM M N, et al. Surface chemical modification of waxy maize starch nanocrystals [J]. Langmuir the Acs Journal of Surfaces & Colloids, 2005, 21(6): 2 425-2 433.
[28] XU Yue, DING Wan-qiang, LIU Ji, et al. Preparation and characterization of organic-soluble acetylated starch nanocry-stals[J]. Carbohydrate Polymers, 2010, 80(4): 1 078-1 084.
[29] SONG Shi-wei, WANG Cai, PAN Ze-lin, et al. Preparation and characterization of amphiphilic starch nanocrystals[J]. Journal of Applied Polymer Science, 2008, 107(1): 418-422.
[30] 王才, 潘则林, 吴美琰, 等. 聚己内酯接枝淀粉纳米晶的制备[J]. 化学通报, 2014, 77(2): 166-169.
[31] NAMAZI H, DADKHAH A. Surface modification of starch nanocrystals through ring-opening polymerization of ε-caprolactone and investigation of their microstructures[J]. Journal of Applied Polymer Science, 2008, 110(4): 2 405-2 412.
[32] REN Li-li, JIANG Man, WANG Li-yan, et al. A method for improving dispersion of starch nanocrystals in water through crosslinking modification with sodium hexametaphosphate[J]. Carbohydrate Polymers, 2012, 87(2): 1 874-1 876.
[33] 陈启杰, 张雄飞. 一种纳米阳离子淀粉的制备方法: 中国, CN103435855A[P]. 2015-07-15.
[34] 陈启杰, 晏永祥, 张雄飞. 一种纳米羧甲基淀粉的制备方法: 中国, CN103467609A[P]. 2015-08-12.
[35] 陈启杰, 张雄飞. 一种纳米两性淀粉的制备方法: 中国, CN103435708A[P]. 2015-11-18.
[36] 陈启杰, 周丽玲, 董徐芳, 等. 淀粉基膜的制备及应用研究进展[J]. 食品与机械, 2017, 33(3): 211-215.
[37] GONZLEZ A, IGARZABAL C I A. Nanocrystal-reinforced soy protein films and their application as active packaging[J]. Food Hydrocolloids, 2015, 43: 777-784.
[38] HLNE Angellier, SONIA Molinaboisseau, PATRICE Dole A, et al. Thermoplastic starch-waxy maize starch nanocrystals nanocomposites[J]. Biomacromolecules, 2006, 7(2): 531-539.
[39] 谢涛, 李晓文, 蒋朝晖, 等. 有机酸—湿热复合处理土豆抗性淀粉糊的理化特性[J]. 食品与机械, 2017, 33(5): 45-49.
[40] RAYNER M, TIMGREN A, SJ M, et al. Quinoa starch granules: a candidate for stabilising food-grade Pickering emulsions.[J]. Journal of the Science of Food & Agriculture, 2012, 92(9): 1 841-1 847.
[41] XIAO Su-yao, XUAN Ming, TONG Chun-yi. Dialdehyde starch nanoparticles as antitumor drug delivery system: An in vitro, in vivo, and immunohistological evaluation[J]. Chinese Science Bulletin, 2012, 57(24): 3 226-3 232.
[42] 吴聪. 纳米大米淀粉的制备及作为药物载体的研究[D]. 天津: 天津科技大学, 2011: 25-26.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.