Abstract
In order to selectively reduce the release amount of aldehyde compounds in mainstream cigarette smoke, the acetylated acetylated cellulose was synthesized on the base of microcrystalline cellulose. According to the aldehyde reduction effect, the synthesis conditions were optimized, and then the synthesized material were added in the cigarette filter tip.Results (1) The optimum synthesis conditions of acetylated acetylated cellulose were: cellulose ion concentration 5%, derivatization reagent molar ratio of diketenecellulose=21, the reaction time 3 h, reaction temperature 110 ℃, DMAP as catalyst. (2) When the acetylated acetylated cellulose material were added a dual-filter of cigarette at the amount of 30 mg/cig, the release of aldehyde compounds in the mainstream smoke was reduced by 21.6%, while conventional mainstream smoke indexes and sensory quality not changed obviously, which showed that the material had perfectly selectively adsorption aldehyde compounds in mainstream cigarette smoke.
Publication Date
9-28-2017
First Page
192
Last Page
196
DOI
10.13652/j.issn.1003-5788.2017.09.040
Recommended Citation
Haiying, QI; Guozheng, LI; Hao, ZHOU; Jianhua, QIU; Chunguang, LI; and Weimin, SONG
(2017)
"Synthesis of acetylated acetylated cellulos materials and application in reducing aldehydes in cigarette mainstream smoke,"
Food and Machinery: Vol. 33:
Iss.
9, Article 40.
DOI: 10.13652/j.issn.1003-5788.2017.09.040
Available at:
https://www.ifoodmm.cn/journal/vol33/iss9/40
References
[1] 谢剑平. 卷烟危害性评价原理与方法[M]. 北京: 化学工业出版社, 2011: 86-90.
[2] World Health Organization. Environmentalhealth criteria 89[M]. Geneva: World Health Organization, 1989: 255.
[3] 段焰青, 者为, 李祖红. 卷烟烟气中 7 种主要有害物质及其危害[J]. 烟草科学研究, 2007(12): 61-64.
[4] 谢剑平, 刘惠民, 朱茂祥, 等. 卷烟烟气危害性指数研究[J]. 烟草科技, 2009(2): 5-15.
[5] 庄亚东, 曹毅, 朱怀远, 等. 卷烟烟气中8种羰基化合物对口腔的刺激作用[J]. 烟草科技, 2014(5): 32-36.
[6] BRANTON P J, MCADAM K G, WINTER D B, et al. Reduction of aldehydes and hydrogen cyanide yields in mainstream cigarette smoke using an amine functionalised ion exchange resin[J]. Chem Cent J, 2011, 5(1): 5-15.
[7] 李绍民, 胡有持, 赵明月, 等. 利用改性Y 型分子筛降低卷烟烟气中的有害成分[J]. 中国烟草学报, 2003, 9(3): 28-39.
[8] 聂聪, 赵乐, 彭斌, 等. 应用后合成法制备的胺基功能化材料降低卷烟主流烟气中挥发性羰基化合物研究[J]. 中国烟草学报, 2010, 16(S1): 50-54.
[9] 解晓翠, 常纪恒, 于川芳, 等. 活性炭结构对卷烟主流烟气化学成分吸附效率的影响[J]. 烟草科技, 2012(9): 31-35.
[10] 吴金凤, 李学刚, 王鹏, 等. 黄连生物碱复合滤嘴选择性降低卷烟烟气中的HCN[J]. 烟草科技, 2012(9): 58-62.
[11] 王程辉, 张丽丽, 徐迎波, 等. 分子印迹材料选择性截留卷烟烟气中芳胺的研究[J]. 光谱实验室, 2010, 27(4): 1 574-1 578.
[12] 杨松, 聂聪, 孙学辉, 等. 聚醋酸乙烯酯大孔吸附树脂选择性降低烟气中苯酚研究[J]. 中国烟草学报, 2013, 19(1): 1-4.
[13] 聂聪, 赵乐, 彭斌, 等. 卷烟滤嘴添加剂减害性能模拟评价装置: 中国, CN200982968Y[P]. 2007-11-28.