•  
  •  
 

Abstract

The total contents of phenolics and flavonoids and the relativeantioxidant and antibacterial activities in different polarity fractions from Atractylodes macrocephala Koidz grown in Qimen (Qi Baizhu) were evaluated. The correlation between total phenolic, flavonoid contents and the antioxidant activities were analyzed. The main constituents of methanol crude extract were identified by gas chromatography-mass spectrometry (GC-MS). The results showed that there were significant differences in the contents of total phenolics and flavonoids, antioxidant and antibacterial activities among different polarity fractions including n-hexane, dichloromethane, ethyl acetate, n-butanol and water fractions (P<0.05). The ethyl acetate fraction had the highest contents of total phenolics \[(139.45±0.19) mg TA/g\] and total flavonoids \[(21.28±2.28) mg QE/g\]. Moreover, it exhibited the strongest reducing power \[(38.95±1.66) mg Vc/g\], ABTS radical scavenging ability \[(302.42±7.51) mg Vc/g\], and DPPH radical scavenging ability \[(51.61±2.59) mg Vc/g\]. The contents of total phenolics and flavonoids demonstrated significant correlations with antioxidant activity (P<0.05). The methanol extract, n-hexane and dichloromethane fractions exerted potent inhibitory effects on E. coli, S. aureus, B. subtilis and P. aeruginos. Hexane fraction presented the best antibacterial effect, and its minimum inhibitory concentration against four common bacterial strains was 1 mg/mL. The methanol crude extract was analyzed by GC-MS, and eighteen compounds were identified, including phenols, alcohols, alkenes and esters, and the major constituents were found to be 3,3'-diamino-4,4'-dihydroxybiphenyl (33.47%), β-eudesmol (28.33%), β-guaiene (5.91%), and 3,3,5,6,7-pentame -thyl-2H-inden-1-one (4.70%).

Publication Date

1-28-2018

First Page

154

Last Page

158,198

DOI

10.13652/j.issn.1003-5788.2018.01.031

References

[1] 岳美颖, 潘媛, 敖慧. 白术化学、药理与临床研究进展[J]. 亚太传统医药, 2016, 12(5): 66-68.
[2] 李云志, 白雪. 祁白术半野生和野生品以及和栽培品化学成分相似性初步研究[J]. 时珍国医国药, 2012, 23(9): 2 241-2 242.
[3] 李云志, 刘兰花, 江洪波. 野生祁白术化学成分的HPLC-ESI-TOF/MS快速分离鉴别[J]. 时珍国医国药, 2013, 24(12): 2 931-2 932.
[4] ZHOU Jue, QU Fan, YU Yong-ping. Chemical and ecological evaluation of a genuine Chinese medicine: Atractylodes macrocephala Koidz[J]. African Journal of Traditional, Complemen-tary and Alternative Medicines, 2011, 8(4): 405-411.
[5] 胡长玉, 陈爱珍, 张慧冲, 等. 安徽野生祁门白术生物学特性研究初报[J]. 黄山学院学报, 2004, 6(6): 80-81.
[6] LI Cui-qin, HE Lang-chong, DONG Hai-yan, et al. Screening for the anti-inflammatory activity of fractions and compounds from Atractylodes macrocephala Koidz[J]. Journal of Ethnopharmacology, 2007, 114(2): 212-217.
[7] 彭伟, 韩婷, 刘青春, 等. 白术地上部分化学成分研究[J]. 中国中药杂志, 2011, 36(5): 578-581.
[8] LI Yun-zhi, DAI Min, PENG Dai-yin. New bisesquiterpenoid lactone from the wild rhizome of Atractylodes macrocephala Koidz grown in Qimen[J]. Natural Product Research, 2017, 31(20): 2 381-2 386.
[9] 张雪青, 邵邻相, 吴文才, 等. 白术挥发油抑菌及抗肿瘤作用研究[J]. 浙江师范大学学报: 自然科学版, 2016, 39 (4): 436-442.
[10] YAO Chun-mei, YANG Xiu-wei. Bioactivity-guided isolation of polyacetylenes with inhibitory activity against NO production in LPS-activated RAW264.7 macrophages from the rhizomes of Atractylodes macrocephala[J]. Journal of Ethnopharmaco-logy, 2014, 151(2): 791-799.
[11] 彭敏, 顾施健, 姜淋洁, 等. 白术提取物降血脂作用的有效部位研究[J]. 时珍国医国药, 2011, 22(10): 2 363-2 365.
[12] 石娜, 苏洁, 杨正标, 等. 白术多糖对D-半乳糖致衰老模型小鼠的抗氧化作用[J]. 中国新药杂志, 2014, 23(5): 577-581.
[13] 胡长玉, 张慧冲, 陈爱珍, 等. 野生祁白术的营养成分分析[J]. 生物学杂志, 2005, 22(3): 37-38.
[14] 胡长玉, 徐有志. 祁白术多糖提取工艺研究[J]. 生物学杂志, 2010, 27(4): 57-59.
[15] KHOUDJA N K, BOULEKBACHE-MAKHLOUF L, MA-DANI K. Antioxidant capacity of crude extracts and their solvent fractions of selected Algerian Lamiaceae[J]. Industrial Crops and Products, 2014, 52: 177-182.
[16] 严鑫, 王委, 刘量. 绶草萃取物体外抗氧化活性及其总酚含量比较[J]. 食品与机械, 2016, 32(8): 143-146.
[17] LARRAURI M, ZUNINO M P, ZYGADLO J A, et al. Chemical characterization and antioxidant properties of fractions separated from extract of peanut skin derived from different industrial processes[J]. Industrial Crops and Products, 2016, 94: 964-971.
[18] 吴永祥, 王祥, 江海涛, 等. 不同极性柳叶蜡梅叶萃取物总酚含量及其抗氧化、抑菌能力研究[J]. 食品与机械, 2017, 33(8): 150-154.
[19] 付晶晶, 肖海芳, 宋元达. 金银花等6种植物提取物总黄酮含量与抗氧化性相关性研究[J]. 食品与机械, 2017, 33(6): 159-163.
[20] SAHREEN S, KHAN M R, KHAN R A. Evaluation of antioxidant activities of various solvent extracts of Carissa opaca fruits[J]. Food Chemistry, 2010, 122(4): 1 205-1 211.
[21] 汪光华, 唐树平, 彭名军, 等. 高良姜中4种黄酮化合物的体外抗氧化能力及抑菌活性研究[J]. 食品与机械, 2017, 33(5): 168-172.
[22] DUBE P, MEYER S, MARNEWICK J L. Antimicrobial and antioxidant activities of different solvent extracts from fermented and green honeybush (Cyclopia intermedia) plant material[J]. South African Journal of Botany, 2017, 110: 184-193.
[23] 高洁, 董文宾, 王勇, 等. 山皂荚多糖的提取工艺及抑菌活性[J]. 食品与机械, 2017, 33(3): 145-149.
[24] 吴永祥, 杨庆, 李林, 等. 豆腐柴叶挥发油化学成分及其抗氧化和抑菌作用研究[J]. 天然产物研究与开发, 2018, 30(1): 45-51.
[25] 孟醒, 李安平, 余江帆, 等. 平卧菊三七提取物体外抗氧化活性研究[J]. 食品与机械, 2016, 32(10): 145-150.
[26] 陆俊, 罗丹, 张佳琦, 等. 三叶木通不同部位多酚、黄酮含量及抗氧化活性比较[J]. 食品与机械, 2016, 32(8): 132-135.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.