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Abstract

In order to study the migration of metal elements Al and Mg into acidic foods in coated paper cups and the effectiveness of mathematical simulation software to simulate migration, eight kinds of coated paper cup samples were digested by wet digestion, and then inductively coupled plasma atomic emission spectrometry (ICP-OES)was used to detect the initial contents of aluminum (Al) and magnesium (Mg) in eight kinds of coated paper cups and their migration into acidic food simulants (3% acetic acid solution). The initial contents of Al and Mg in 8 paper cups were 841.6~3 482.0 and 179.1~19 720.1 mg/kg, respectively. Under the migration condi-tions of 40 ℃/ 12 h, the migration of metal elements Al and Mg into 3% acetic acid solution in the 8 samples was 0.077~0.212 and 0.065~0.862 mg/kg, and at 70 ℃/8 h, the migration of metal elements Al and Mg into 3% acetic acid solution was 0.074~0.180 and 0.064~2.209 mg/kg, respectively. The thickness of the LDPE layer, the migration temperature and time, and the thickness and density of the paper can also affect the migration of the two metal elements. Using the migration simulation software AKTS-SML, simulation of Al and Mg migration were carried out. Piringer model was used to calculate the diffusion coefficients. The partition coefficient between paper and low density polyethylene (LDPE) was set to 1 000, The partition coefficient between LDPE and food simulants (3% acetic acid) was set to 1, the migration of metal elements Al and Mg simulated at 40 ℃/12 h were 0.760~3.075 and 0.162~17.750 mg/kg respectively; the migration simulation results at 70 ℃/8 h were 0.757~3.059 and 0.161~17.660 mg/kg, the migration results simulated by the software are higher than those obtained by the experiment, migration simulation software can simulate the migration of metal elements Al and Mg to some extent.

Publication Date

10-28-2018

First Page

95

Last Page

99

DOI

10.13652/j.issn.1003-5788.2018.10.020

References

[1] 郎贤忠, 潘宏伟, 杨慧丽, 等. 完全生物降解聚乳酸流延纸塑复合材料的制备及性能研究[J]. 塑料工业, 2016(4): 124-128.
[2] 彭湘莲, 付红军. 食品纸塑复合包装材料中汞含量测定条件的优化[J]. 食品与机械, 2015, 31(5): 62-65.
[3] 袁玮, 侯庆喜, 赵江鹏, 等. 镁在制浆造纸工业中的应用[J]. 纸和造纸, 2009(8): 45-49.
[4] 彭湘莲, 李忠海, 王利兵, 等. 4种纸塑包装容器中重金属镉的迁移规律研究[J]. 中国食品学报, 2012(9): 73-77.
[5] 赵付文, 孙卓军, 高国庆, 等. 食品接触塑料材料中有害重金属迁移量测定方法综述[J]. 化学分析计量, 2015(1): 101-105.
[6] SANTOS  J D, OLIVEIRA F M P, HERRMANN A B, et al. ICP OES determination of contaminant elements leached from food packaging films[J]. Brazilian Archives of Biology and Technology, 2017, 60: e17160465.
[7] GRANK J. The mathematics of diffusion[M]. 2nd ed. Oxford: Oxford University Press, 1975.
[8] BRANDSCH J, MERCEA P, RTER M, et al. Migration modelling as a tool for quality assurance of food packaging[J]. Food Additives & Contaminants, 2002, 19(s1): 29.
[9] BEGLEY T, CASTLE L, FEIGENBAUM A, et al. Evaluation of migration models that might be used in support of regulations for food-contact plastics[J]. Food Additives & Contaminants, 2005, 22(1): 73-90.
[10] STOFFERS N H, BRANDSCH R, BRADLEY E L, et al. Feasibility study for the development of certified reference materials for specific migration testing Part 2: estimation of diffusion parameters and comparison of experimental and predicted data[J]. Food Additives & Contaminants, 2005, 22(2): 173-184.
[11] WELLE F, FRANZ R. Migration of antimony from PET bottles into beverages: determination of the activation energy of diffusion and migration modelling compared with literature data[J]. Food Additives & Contaminants, 2011, 28(1): 115-126.
[12] TORRES A, RAMIREZ C, ROMERO J, et al. Experimental and theoretical study of bisphenol A migration from polycarbonate into regulated EU food simulant[J]. European Food Research & Technology, 2015, 240(2): 335-343.
[13] BRANDSCH R. Probabilistic migration modelling focused on functional barrier efficiency and low migration concepts in support of risk assessment[J]. Food Additives & Contaminants Part A, 2017, 34(10): 1-24.
[14] HELMROTH E, RIJK R, DEKKER M, et al. Predictive modelling of migration from packaging materials into food products for regulatory purposes[J]. Trends in Food Science & Technology, 2002, 13(3): 102-109.
[15] 巴恩斯, 辛克莱, 沃森, 等. 食品接触材料及其化学迁移[M]. 宋欢, 林勤保, 译. 北京: 中国轻工业出版社, 2011: 125-141.
[16] TEHRANY E A, FOURNIER F, DESOBRY S. Simple method to calculate partition coefficient of migrant in food simulant/polymer system[J]. Journal of Food Engineering, 2006, 77(1): 135-319.
[17] GILLET G, VITRAC O, DESOBRY S. Prediction of partition coefficients of plastic additives between packaging materials and food simulants[J]. Industrial & Engineering Chemistry Research, 2010, 49(16): 7 263-7 280.
[18] European Commission. Commission Directive 2002/72/EC of 6 August 2002 on Plastic materials and articles intended to come into contact with foodstuffs[S]. Brussels: Official Journal of the European Communities, 2002: L220/18.
[19] European Commission. Commission Regulation (EU) No.10/2011 of 14 January 2011 on Plastic materials and articles intended to come into contact with food[S]. Brussels: Official Journal of the European Union, 2011: L12/82-85.
[20] 丁从阳, 林勤保, 钟怀宁, 等. AKTS-SML软件预测5种塑料薄膜中有机助剂向脂肪食品模拟液的迁移[J]. 食品科学, 2018(8): 256-261.
[21] 黄秀玲. 纸塑复合包装材料UV墨光引发剂迁移试验与理论研究[D]. 无锡: 江南大学, 2009: 70-112.
[22] POCAS M D F, OLIVIRA J C, PEREIRA J R, et al. Modelling migration from paper into a food simulant[J]. Food Control, 2011, 22(2): 303-312.
[23] 彭湘莲. 食品纸塑复合包装材料中重金属的检测及迁移规律研究[D]. 长沙: 中南林业科技大学, 2015: 111-140.
[24] HUANG Xiu-lin, WANG Zhi-wei, HU Chang-ying, et al. Factors affecting migration of contaminants from paper through polymer coating into food simulants[J]. Packaging Technology and Science, 2013, 26: 23-31.

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