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Abstract

To improve the yield and quality of Osmanthus extracts, several techniques were applied including the enzymatic hydrolysis by β-glucosidase and pectinase complex along with petroleum ether extraction and GC-MS analysis. The enzymatic hydrolysis process was optimized usingresponse surface methodology, and a reliable multiple quadratic regression model was established. The results showed that the best levels of the factors were as followed: pH 4.7, time 2.6 h, temperature 46 ℃, ratio of material to liquid 19.81 (mL/g), and the amount of enzyme complex 54.4 IU/g with 48.1% β-glucosidase activity, which was confirmed by experiments with an extraction yield of 3.32%, an increment of 62.75% compared to direct extraction. The results of GC-MS indicate an increase of main compounds, revealing that the hydrolysis by enzyme complex is more effective than direct extraction in terms of the extraction quality improvement. Compared with the control, the contents of the main aroma substances ,such as dihydrolinalool, γ-decalactone, dihydro-β-ionone, β-ionone, geraniol, and limonene, were increased by 27.27%, 116.36%, 100.00%, 247.06%, 72.84% and 14.29%, respectively. Meanwhile, nerolidol and β-ionol were also detected by GC-MS. After treating by β-glucosidase-pectinase enzyme, the yield and aroma quality of Osmanthus abstracts improved effectively.

Publication Date

6-28-2018

First Page

180

Last Page

186

DOI

10.13652/j.issn.1003-5788.2018.06.036

References

[1] YUAN Wang-jun, HAN Yuan-ji, DONG Mei-fang, et al. Assessment of genetic diversity and relationships among Osmanthus fragrans cultivars using AFLP markers[J]. Electron. J. Biotechnol, 2011, 14(1): 1-9.
[2] 胡春弟, 张锦红, 徐亮, 等. 桂花总黄酮的提取及抗氧化能力研究[J]. 食品与机械, 2009, 25(2): 71-73.
[3] WU Li-chen, CHANG Li-hui, CHEN Si-han, et al. Antioxidant activity and melanogenesis inhibitory effect of the acetonic extract of Osmanthus fragrans: a potential natural and functional food flavor additive[J]. LWT-Food Sci. Technol., 2009, 42(9): 1 513-1 519.
[4] TSAI P J, TSAI T H, YU C H, et al. Comparison of NO-scavenging and NO-suppressing activities of different herbal teas with those of green tea[J]. Food Chem., 2007, 103(1): 181-187.
[5] LEE D G, LEE S M, BANG M H, et al. Lignans from the flowers of Osmanthus fragrans var. aurantiacus and their inhibition effect on NO production[J]. Arch. Pharm. Res., 2011, 34(12): 2 029-2 035.
[6] HUNG C Y, TSAI Y C, LI Kuo-yu. Phenolic antioxidants isolated from the flowers of Osmanthus fragrans[J]. Molecules, 2012, 17(12): 10 724-10 737.
[7] 汪海波, 靳熙茜. β-葡萄糖苷酶水解制备桂花浸膏的新工艺研究[J]. 食品科学, 2008, 29(11): 324-327.
[8] 夏雪娟, 冉春霞, 李冠楠, 等. 金桂和丹桂挥发油的超临界CO2萃取和GC-MS分析[J]. 中国粮油学报, 2015, 30(9): 66-71.
[9] CAI Xuan, MAI Rong-zhang, ZOU Jing-jing, et al. Analysis of aroma-active compounds in three sweet Osmanthus (Osmanthus fragrans) cultivars by GC-olfactometry and GC-MS[J]. Journal of Zhejiang University Science, 2014, 15(7): 638-648.
[10] HU Chun-di, LIANG Yi-zeng, LI Xiao-ru, et al. Essential oil composition of Osmanthus fragrans varieties by GC-MS and heuristic evolving latent projections[J]. Chromatographia, 2009, 70: 1 163-1 169.
[11] 黄英, 刘晓博, 司辉清. 腊梅花精油的提取方法与应用前景[J]. 北方园艺, 2013(4): 188-191.
[12] ARAUS K, UQUICHE E, DEL VALLE J M. Matrix effects in supercritical CO2 extraction of essential oils from plant material[J]. Journal of Food Engineering, 2009, 92(4): 438-447.
[13] POURMORTAZAVI S M, HAJIMIRSADECHI S S. Supercritical fluid extraction in plant essential and volatile oil analysis[J]. Journal of Chromatography A, 2007, 1 163(12): 2-24.
[14] 解万翠, 汤坚, 罗昌荣, 等. 糖苷类香料前驱体研究进展[J]. 香料香精化妆品, 2004(4): 25-27, 30.
[15] 耿敬章. 响应面优化水酶法提取桂花油及其微胶囊化工艺研究[J]. 粮食与油脂, 2015, 28(9): 27-30.
[16] 杨志萍, 姚卫蓉, 钱和. β-D-葡萄糖苷酶对桂花香气成分的影响[J]. 精细化工, 2005, 22(12): 924-926.
[17] 张雪松, 裴建军, 赵林果, 等. 不同酶处理对桂花浸膏及精油成分的影响[J]. 现代食品科技, 2017, 33(4): 254-261.
[18] 陶清, 徐德虚, 吕鉴泉. 超临界CO2萃取桂花油的工艺研究[J]. 食品研究与开发, 2007, 28(7): 57-60.
[19] CABRITA M J, FREITAS A M C, LAUREANO O, et al. Glycosidic aroma compounds of some Portuguese grape cultivars[J]. Journal of the Science of Food and Agriculture, 2006, 86: 922-931.

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