Abstract
As a new extraction technology, subcritical fluid extraction has received more and more attention, due to its high efficiency and quality. The paper first introduces the basic principle of subcritical fluid extraction, and analyzes the effects of extraction solvent, temperature and pressure, time and frequency, and volume of solvent on the extraction efficiency. Furthermore, the kinetics and thermodynamics of the subcritical fluid extraction process are explained. Then, the quality of the oils obtained by subcritical fluid extraction and other extraction techniques is compared, indicating the migration of bioactive concomitants in the subcritical fluid. Finally, the future research direction of subcritical fluid extraction theory is prospected.
Publication Date
7-28-2018
First Page
164
Last Page
168,220
DOI
10.13652/j.issn.1003-5788.2018.07.034
Recommended Citation
Qifei, WU; Jiachen, SHI; Jun, SUN; Zhongwei, CHEN; and Bin, XU
(2018)
"Curren tstatus and trends of theoretical research on subcritical fluid extraction of agricultural products,"
Food and Machinery: Vol. 34:
Iss.
7, Article 34.
DOI: 10.13652/j.issn.1003-5788.2018.07.034
Available at:
https://www.ifoodmm.cn/journal/vol34/iss7/34
References
[1] LIU Zeng-gen, MEI Li-juan, WANG Qi-lan, et al. Optimization of subcritical fluid extraction of seed oil from Nitraria tangutorum, using response surface methodology[J]. LWT-Food Science and Technology, 2014, 56(1): 168-174.
[2] ROSENTHAL H, TREVITHICK H P. Low boiling hydrocarbons as oil extraction media[J]. Oil & Soap, 1934, 11(7): 133-134.
[3] 祁鲲. 亚临界低温萃取技术在天然产物提取中的应用及前景[C]// 首届中国亚临界生物萃取技术发展论坛论文集. 安阳: 中国国际科技促进会， 国家级安阳高新技术产业开发区管委会， 河南省亚临界萃取设备工程技术研究中心, 2016: 68-74.
[4] 宋国辉, 黄纪念, 孙强, 等. 加压液化气亚临界萃取技术在农产品加工中的应用[J]. 农产品加工: 学刊, 2014(8): 62-66.
[5] 程能林. 溶剂手册[M]. 北京: 化学工业出版社, 2015: 107-110.
[6] 张思, 谢红旗, 刘雪辉, 等. 超临界及亚临界萃取澳洲薄荷挥发性成分的对比[J]. 食品与机械, 2016, 32(10): 137-139.
[7] 詹少颖, 何静仁, 常琳萍, 等. 亚临界提取蜜桔皮精油成分分析及其微乳液制备[J]. 食品与机械, 2017, 33(7): 160-164.
[8] 常大伟, 孙娇娇, 刘树兴. 利用亚临界萃取技术提取生姜中的姜油[J]. 食品与机械, 2015, 31(1): 159-163.
[9] HOSHINO M, KAWAMOTO Y, YAMATO K, et al. Application of a DME extraction method to agricultural produce[C]// Joint International Symposium on「regional Revitalization and Innovation for Social Contribution」and「e-Asia Functional Materials and Biomass Utilization 2015」. Tagawa: [s.n.], 2015: 10-11.
[10] 姚茂君, 李静. 牡丹籽油亚临界流体萃取工艺优化[J]. 食品科学, 2014, 35(14): 53-57.
[11] 刘日斌, 汪学德, 胡华丽, 等. 芝麻油亚临界流体低温萃取工艺及品质研究[J]. 河南工业大学学报: 自然科学版, 2014, 35(1): 30-36.
[12] 万楚筠, 黄凤洪, 张明,等. 亚临界流体萃取胡麻籽低温压榨饼中油脂[J]. 农业工程学报, 2014, 30(21): 324-331.
[13] 廖传华, 黄振仁. 超临界CO2流体萃取技术: 工艺开发及其应用[M]. 北京: 化学工业出版社, 2004: 23-40.
[14] 张明, 万楚筠, 黄凤洪. 亚临界萃取菜籽脱皮低温压榨饼中油脂[J]. 中国油脂, 2015, 40(5): 14-17.
[15] SO G C, MACDONALD D G. Kinetics of oil extraction from canola (rapeseed)[J]. Canadian Journal of Chemical Engineering, 2010, 64(1): 80-86.
[16] SUN Jun, SHI Jia-chen, MU Yao-yao, et al. Subcritical butane extraction of oil and minor bioactive components from soybean germ: Determination of migration patterns and a kinetic model[J]. Journal of Food Process Engineering, 2018(2018-05-10). https://doi.org/10.1111/jfpe.12697.
[17] 曹雁平, 朱雨辰. 植物有效成分间歇浸取动力学研究进展[J]. 食品科学技术学报, 2011, 29(6): 20-26.
[18] HUANG Zhen, SHI Xiao-han, JIANG Wei-juan. Theoretical models for supercritical fluid extraction[J]. Journal of Chromatography A, 2012, 1 250(15): 2-26.
[19] ERICA R Baümler, MARA E Carrín, AMALIA A Carelli. Extraction of sunflower oil using ethanol as solvent[J]. Journal of Food Engineering, 2016, 178: 190-197.
[20] FERNNDEZ M B, PEREZ E E, CRAPISTE G H, et al. Kinetic study of canola oil and tocopherol extraction: Parameter comparison of nonlinear models[J]. Journal of Food Engineering, 2012, 111(4): 682-689.
[21] KRISHNAN R Y, RAJAN K S. Microwave assisted extraction of flavonoids from Terminalia bellerica: Study of kinetics and thermodynamics[J]. Separation & Purification Technology, 2016, 157: 169-178.
[22] CRANK J. The Mathematics of Diffusion[M]. 2nd ed. Oxford: Clarendon Press, 1975: 1-89.
[23] 陈中伟, 赵芳芳, 丁芬, 等. 亚临界丙烷萃取米糠油及其微量活性组分动力学模型[J]. 农业工程学报, 2016, 32(19): 280-286.
[24] DAOOD H G, ILLS V, GNAYFEED M H, et al. Extraction of pungent spice paprika by supercritical carbon dioxide and subcritical propane[J]. Journal of Supercritical Fluids, 2002, 23(2): 143-152.
[25] DARRELL S, RAFAEL H, MARK Z, et al. Extraction of rice brain oil using supercritical carbon dioxide and propane[J]. Journal of the American Oil Chemists Society, 2006, 83(10): 885.
[26] DOS S F L, DE OLIVEIRA J V, DARIVA C, et al. Extrac-tion of grape seed oil using compressed carbon dioxide and propane: extraction yields and characterization of free glycerol compounds[J]. Journal of Agricultural and Food Chemistry, 2008, 56(8): 2 558-2 564.
[27] HAMDAN S, DAOOD H G, TOTH-MARKUS M, et al. Extraction of cardamom oil by supercritical carbon dioxide and sub-critical propane[J]. Journal of Supercritical Fluids, 2008, 44(1): 25-30.
[28] CORSO M P, FAGUNDES-KLEN M R, SILVA E A, et al. Extraction of sesame seed (Sesamun indicum, L.) oil using compressed propane and supercritical carbon dioxide[J]. Journal of Supercritical Fluids, 2010, 52(1): 56-61.
[29] PEDERSSETTI M M, PAL F, DA S E, et al. Extraction of canola seed (Brassica napus) oil using compressed propane and supercritical carbon dioxide[J]. Journal of Food Engineering, 2011, 102(2): 189-196.
[30] NIMET G, SILVA E A D, PAL F, et al. Extraction of sunflower (Heliantus annuus, L.) oil with supercritical CO2, and subcritical propane: Experimental and modeling[J]. Chemical Engineering Journal, 2011, 168(1): 262-268.
[31] RUTTARATTANAMONGKOL K, PETRASCH A. Oxida-tive susceptibility and thermal properties of moringa oliefera seed oil obtained by pilot-scale subcritical and supercritical carbon dioxide extraction[J]. Journal of Food Process Engineering, 2016, 39(3): 226-236.
[32] 周世龙. 大豆胚芽油的亚临界丁烷萃取特性研究[D]. 镇江: 江苏大学, 2014: 21-26.
[33] XU Bin, HAN Ji-hua, ZHOU Shi-long, et al. Quality characteristics of wheat germ oil obtained by innovative subcritical butane experimental equipment[J]. Journal of Food Process Engineering, 2016, 39(1): 79-87.
[34] 陈中伟, 丁芬, 吴其飞, 等. 亚临界丙烷、超临界CO2及正己烷对米糠油提取品质的对比研究[J]. 中国粮油学报, 2017, 32(3): 36-41.
[35] 丁芬. 分级米糠品质及其油脂的亚临界丙烷萃取特性研究[D]. 镇江: 江苏大学, 2015.
[36] KIM M J, PARK J W, JI Y K, et al. Effects of heat treatment and visible light exposure on the oxidative: stability of rice bran and of rice bran oil[J]. Food Science & Biotechnology, 2013, 22(5): 1 223-1 228.