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Abstract

We used 50/30 μm DVB/CAR/PDMS, 75 μm CAR/PDMS, 65 μm PDMS/DVB, 100 μm PDMS to enrich and concentrate aroma components of Rosa roxburghii Tratt juice for improving the accuracy and reliability of analyzing the aroma components by gas chromatography and comparing the consequence and sensitivity of extracting the aroma components by different fiber coating extractors. The aroma components of Rosa roxburghii Tratt juice were detected by GC-MS. We compared the quantity and content of aroma components by principal component analysis (PCA) and established the evaluation model of aroma quality. The results showed that: esters, alcohols, and terpenes were the main aroma components of Rosa roxburghii Tratt juice. There were significant differences in the compounds extracted by different extraction heads. Fifty-nine compounds were extracted by 50/30 μm DVB/CAR/PDMS with a relative content up to 93.96%. The contents of esters and alcohols were highest in aromatic materials. Thirty-eight compounds were extracted by 65 μm PDMS/DVB with a relative content of 91.19%; twenty-two compounds were extracted by 100 μm PDMS with a relative content of 92.79%; twenty-six compounds were extracted by 75 μm CAR/PDMS with a relative content of 92.08%. Among the four fiber coating extraction heads, 50/30 μm DVB/CAR/PDMS was the best extraction fiber for the aroma components of the Rosa roxburghii Tratt juice.

Publication Date

1-28-2019

First Page

47

Last Page

53

DOI

10.13652/j.issn.1003-5788.2019.01.009

References

[1] CHEN Guang-jing, KAN Jian-quan. Characterization of a novel polysaccharide isolated from Rosa roxburghii Tratt fruit and assessment of its antioxidant in vitro and in vivo[J]. International Journal of Biological Macromolecules, 2017, DOI:10.1016/j.ijbiomac.2017.08.160.
[2] 吴彩霞, 刘红丽, 卢素格, 等. 固相微萃取法与水蒸气蒸馏法提取蜘蛛香挥发油成分的比较[J]. 中国药房, 2008(12): 918-920.
[3] 乔宇, 程薇, 王少华, 等. 溶剂萃取法和固相微萃取法分析比较锦橙汁的香气成分[J]. 农产品加工: 创新版, 2010(2): 17-21.
[4] 赵谋明, 曹永, 蔡宇, 等. SDE和HS-SPME法与GC-MS/O联用分析阳江豆豉的香气活性化合物[J]. 现代食品科技, 2016(5): 264-275.
[5] SHI Jiang, WANG Li, MA Cheng-ying, et al. Changes of aroma components in black tea made from fresh leaves induced by methyl jasmonate[J]. Journal of Zhejiang University-Science B: Biomedicine & Biotechnology, 2014(4): 313-321.
[6] 高琦, 张建超, 陈佳男, 等. 基于主成分分析法综合评价四种干燥方式对山药脆片香气品质的影响[J]. 食品科学, 2018, 39(20): 175-181.
[7] 席嘉佩, 詹萍, 田洪磊, 等. 基于SPME-GC-MS 和 PCA 的不同萃取头对新疆烤羊肉香气成分萃取效果比较[J]. 食品科学, 2018, 39(10): 234-241.
[8] 李宝丽, 邓建玲, 蔡欣, 等. 顶空固相微萃取-气质联用结合主成分分析研究纯葡萄汁的香气成分[J]. 中国食品学报, 2016, 16(4): 258-270.
[9] XU Chang-hua, CHEN Guo-sheng, XIONG Zhen-hai, et al. Applications of solid-phase microextraction in food analysis[J]. TrAC Trends in Analytical Chemistry, 2016, 80(6): 12-29.
[10] 周志, 徐永霞, 胡昊, 等. 顶空固相微萃取和同时蒸馏萃取应用于GC-MS分析野生刺梨汁挥发性成分的比较研究[J]. 食品科学, 2011, 32(16): 279-282.
[11] 彭邦远, 张洪礼, 孙小静, 等. 热处理刺梨汁香气物质的SPME-GC-MS检测与主成分分析[J]. 食品科学, 2018, 39(6): 230-236.
[12] 张丹, 韦广鑫, 王文, 等. 安顺普定刺梨与无籽刺梨营养成分及香气物质比较研究[J]. 食品工业科技, 2016, 37(12): 149-154, 177.
[13] 付慧晓, 王道平, 黄丽荣, 等. 刺梨和无籽刺梨挥发性香气成分分析[J]. 精细化工, 2012, 29(9): 875-878.
[14] DEUSSING Guido. 顶空技术探究——不断提高分析灵敏度的顶空技术[J]. 实验与分析, 2013(2): 48-50.
[15] ANGELIKA Z, ERWIN W, HENRYK H, et al. Differentiation of wines according to grape variety and geographical origin based on volatiles profiling using SPME-MS and SPME-GC/MS methods[J]. Food Chemistry, 2016, DOI:10.1016/j.foodchem.2016.06.120.
[16] TARA T, PIERGIORGIO C, IVA S, et al. Optimization of wine head-space analy sis by solid-phase microex traction capillary gas chromatog raphy with mass spectrometric and flame ionization detection[J]. Food Chemistry, 2005, 93: 361-369.
[17] 刘非, 杜丽平, 肖冬光. 酱油挥发性成分固相微萃取条件的优化[J]. 食品与发酵工业, 2017, 43(7): 70-75.
[18] KORTESSERRANO De la Hoz, MARIA Rosario Salinas, ALESSANDRA Ferrandinob. Different coatings for the HS-SBSE grape volatile analysis in model solution: Preliminary results[J]. Food Chemistry, 2016, 212(12): 814-820.
[19] 卢静茹, 林向阳, 张如, 等. HS-SPME-GC-MS联用分析美国巴旦木香气成分[J]. 食品科学, 2015, 36(2): 120-125.
[20] 钟海雁, 黄永辉, 龙奇志, 等. SPME萃取头对茶油挥发物萃取效果的影响[J]. 中国粮油学报, 2008(4): 143-148.
[21] 刘敬科, 张爱霞, 李少辉, 等. 顶空固相微萃取-气相色谱-质谱法测定小米黄酒风味成分[J]. 色谱, 2017, 35(11): 1 184-1 191.
[22] WANG Yi-ju, YANG Chun-xiang, LI Shao-hua, et al. Volatile characteristics of 50 peaches and nectarines evaluated by HP-SPME with GC-MS[J]. Food Chemistry, 2009, DOI:10.1016/j.foodchem.2009.02.004.
[23] SUMITANI H, SUEKANE S, NAKATANI A, et al. Changes in composition of volatile compounds in high pressure treated peach[R]. Toyo Junior College of Food Technology and Toyo Institute of Food Technology, 1996, 42(3): 77-89.
[24] KANG Wen-huai, LI Yan, XU Yan, et al. Characterization of aroma compounds in Chinese bayberry (Myricarubra sieb. et Zuce.) by gas chromatography Mass spectrometry (GC-MS) and olfactometry (GC-O)[J]. J Food Sci, 2012, 77(10): 1 030-1 035.
[25] 周立华, 牟德华, 李艳. 7种小浆果香气物质的 GC-MS 检测与主成分分析[J]. 食品科学, 2017, 38(2): 184-190.
[26] 周志, 马琼, 朱玉昌, 等. GC-O-MS法分析野生刺梨汁游离态和O-糖苷键合态香气活性物质[J]. 食品科学, 2015, 36(22): 80-84.
[27] 范文来, 徐岩. 白酒79个风味化合物嗅觉阈值测定[J]. 酿酒, 2011(6): 80-84.
[28] PANG Xue-li, GUO Xing-feng, QIN Zi-han, et al. Identification of aroma-active com-pounds in jiashi muskmelon juice by GC-O-MS and OAV calculation[J]. J Agr Food Chem, 2012, 60(17): 4 179-4 185.
[29] TAT L, COMUZZO P, STOLFO I, et al. Optimization of wine headspace analysis by solid-phase microextraction capillary gas chromatography with mass spectrometric and flame ionization detection[J]. Food Chemistry, 2005, 93(2): 361-369.

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