Abstract
The effect and mechanism of decolorization were studied with magnesium sulfate and amphoteric 2% polysilicate zinc on the brown granulated syrup under high pH conditions. The factors and levels of response surface analysis were determined on the basis of single factor tests. The decolorization process was optimized by response surface analysis to obtain the optimum process conditions: magnesium sulfate of 500 mg/L, dosage of 2% silica polysilicic acid zinc of 1.57%, and pH 11. Under this condition, the decolorization rate reached 92.21%. The composites and sugar juice system were characterized by scanning electron microscopy (SEM) and potential analyzer. The results showed that the decolonization mechanism was electric neutralization and adsorption.
Publication Date
2-28-2019
First Page
55
Last Page
61
DOI
10.13652/j.issn.1003-5788.2019.02.011
Recommended Citation
Weixia, LI; Lijun, LI; Lanfeng, YANG; Xiang, MAO; and Hao, CHENG
(2019)
"Technology and mechanism of decolorization for brown granulated sugar by magnesium sulfate-zinc polysilicate method,"
Food and Machinery: Vol. 35:
Iss.
2, Article 11.
DOI: 10.13652/j.issn.1003-5788.2019.02.011
Available at:
https://www.ifoodmm.cn/journal/vol35/iss2/11
References
[1] 李利军, 李青松, 孔红星, 等. 赤砂糖回溶糖浆两步法澄清脱色工艺的研究[J]. 食品科技, 2013, 38(2): 65-69.
[2] SARIR E M, PABON B R. High performance decolorants and color precipitants for VHP sugar production[J]. International Sugar Journal, 2017, 119(1 421): 368-372.
[3] 王元刚, 刘诗雨, 赵建海, 等. 氢氧化镁混凝过程应用于活性黄X-R废水脱色研究[J]. 环境工程, 2015, 33(7): 61-65.
[4] ZHANG Meng, SONG Wei-qiang, CHEN Qiu-ling, et al. One-pot synthesis of magnetic Ni@Mg(OH)2 core-shell nanocomposites as a recyclable removal agent for heavy metals[J]. Acs Appl Mater Interfaces, 2015, 7(3): 1 533-1 540.
[5] LI Chao-ran, ZHUANG Zan-yong, HUANG Feng, et al. Recycling rare earth elements from industrial wastewater with flowerlike nano-Mg(OH)2[J]. Acs Appl Mater Interfaces, 2013, 5(19): 9 719-9 725.
[6] 李利军, 李青松, 孔红星, 等. 赤砂糖回溶糖浆两步法澄清脱色工艺的研究[J]. 食品科技, 2013, 38(2): 65-69.
[7] 马月飞, 黄悦刚. 氢氧化镁应用于亚法糖汁澄清过程的初步研究[J]. 广西轻工业, 2005(1): 17-19.
[8] LUO Yu-qing, LI Chao, ABBASI A M, et al. Screening of bioflocculant-producing bacteria and its application in clarification process of sugarcane juice[J]. International Sugar Journal, 2016, 118(1 405): 34-40.
[9] 袁天佑, 刘和清, 谭承德, 等. 聚硅酸盐絮凝剂对甘蔗混合汁脱色效率的研究[J]. 甘蔗糖业, 2000(1): 33-37.
[10] 刘和清. PSAZ-亚硫酸法澄清新工艺试验[J]. 广西蔗糖, 1996(3): 51-54.
[11] 刘淑云. 聚硅酸硫酸铜锌絮凝剂的制备及其在造纸废水中的应用研究[D]. 长沙: 湖南大学, 2006: 31-32.
[12] 李墉, 郑长庚. 甘蔗制糖化学管理分析方法[M]. 北京: 轻工业出版社, 1995: 59-76.
[13] 高宝玉, 王燕, 岳钦艳, 等. 聚合铝基复合絮凝剂的电荷特性及絮凝作用[J]. 环境科学, 2003(1): 103-106.
[14] YE Lan-lan, LI Feng, WU Tao, et al. Rapid and effective removal of sodium lignosulfonate from aqueous solutions by in-situ formed magnesium hydroxide[J]. Korean Journal of Chemical Engineering, 2016, 33(12): 1-9.
[15] LEE K E, MORAD N, TENG T T, et al. Development, characterization and the application of hybrid materials in coagulation/flocculation of wastewater: A review[J]. Chemical Engineering Journal, 2012, 203(5): 370-386.
[16] 高宝玉, 王燕, 岳钦艳, 等. 聚合铝基复合絮凝剂的电荷特性及絮凝作用[J]. 环境科学, 2003(1): 103-106.
[17] SASKA M, ZOSSI B S, 刘慧霞, 等. 石灰法、亚硫酸法和碳酸法清净对蔗汁脱色(下)[J]. 甘蔗糖业, 2013(4): 31-35.
[18] LEE K E, MORAD N, TENG T T, et al. Development, characterization and the application of hybrid materials in coagulation/flocculation of wastewater: A review[J]. Chemical Engineering Journal, 2012, 203(5): 370-386.
[19] 王雪枫, 黄雪莉, 李培. 聚硅酸锌絮凝剂的制备工艺及絮凝性能研究[J]. 水处理技术, 2013, 39(1): 33-36.
[20] WU Can, LIU Wei-zhen, ZHANG Jing, et al. Mechanisms of synergistic removal of low concentration As(V) by nZVI@Mg(OH)2 nanocomposite[J]. Journal of Physical Chemistry C, 2017, DOI: 10.1021/acs.jpcc.7b06356.
[21] WANG Zhi-ping, LI Chun-hui, MU Yan, et al. Nanoadduct relieves: Alleviation of developmental toxicity of Cr(VI) due to its spontaneous adsorption to Mg(OH)2 nanoflakes[J]. Journal of Hazardous Materials, 2015, 287: 296-305.
[22] GRADY Hanrahan, KENNETH Lu. Application of factor-ial and response surface methodology in modern experim-ental design and optimization[J]. Critical Reviews in Analytical Chemistry, 2006, 36(3/4): 141-151.
[23] SALEEM M M, SOM A. Design of experiments based factorial design and response surface methodology for MEMS optimiza-tion[J]. Microsystem Technologies, 2015, 21(1): 263-276.
[24] 何惠欢, 梁贤慧, 陆登俊. 亚硫酸法甘蔗糖厂澄清工艺条件对蔗汁除酚和脱色效果的影响[J]. 食品工业, 2015, 36(5): 112-115.
[25] SASKA M, ZOSSI B S, 刘慧霞, 等. 石灰法、亚硫酸法和碳酸法清净对蔗汁脱色(上)[J]. 甘蔗糖业, 2013(2): 33-36.
[26] LI Hai-yan, LIU Shi-yu, ZHAO Jian-hai, et al. Removal of reactive dyes from wastewater assisted with kaolin clay by magnesium hydroxide coagulation process[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2016, 494: 222-227.
[27] 许小洁, 吴纯德, 叶健, 等. 基于Zeta电位的硅藻土复配剂强化混凝研究[J]. 环境科学与技术, 2010, 33(10): 151-153.