Research progress on degradation technology of harmful gases in granary

Authors

PAN Di, College of Food Science and Engineering, Beijing University of Agriculture, Beijing 102206 , China
MA Ting-jun, College of Food Science and Engineering, Beijing University of Agriculture, Beijing 102206 , China
KANG Kai, Research Institute of Chemical Defense, Beijing 100083 , China
BAI Shu-pei, Research Institute of Chemical Defense, Beijing 100083 , China

Abstract

There were many harmful gases in the process of storing grain in large granaries, which can not only cause environmental pollutions, but also endanger people's health. Reducing harmful gases in granaries and ensuring grain quality had become the focus of food storage industry. In this paper, the sources, types and harms of harmful gases produced in the process of grain storage were briefly described, and the relative degradation methods, principles, advantages and disadvantages of phosphine, were also introduced in detail. Furthermore, the feasibility of degradation of harmful gases in granary by plasma technology was emphasized, and the problems to be solved in practical application of this technology were raised.

Publication Date

1-28-2020

First Page

230

Last Page

236

DOI

10.13652/j.issn.1003-5788.2020.01.040

Recommended Citation

Di, PAN; Ting-jun, MA; Kai, KANG; and Shu-pei, BAI (2020) "Research progress on degradation technology of harmful gases in granary," Food and Machinery: Vol. 36: Iss. 1, Article 40.
DOI: 10.13652/j.issn.1003-5788.2020.01.040
Available at: https://www.ifoodmm.cn/journal/vol36/iss1/40

References

[1] 胡丽华,郭敏,张景虎,等.储粮害虫检测新技术及应用现状[J].农业工程学报,2007,23(11):286-290.
[2] ROZMAN V,KALINOVIC I,KORUNIC Z.Toxicity of naturally occurring compounds of Lamiaceae and Lauraceae to three stored-product insects[J].Journal of Stored Products Research,2007,43(4):349-355.
[3] ZHOU Li-yang,WANG Shao-jin.Verification of radio frequency heating uniformity and Sitophilus oryzae control in rough,brown,and milled rice[J].Journal of Stored Products Research,2016,65:40-47.
[4] 李新宇,熊旭波,张岩,等.热管低温储粮技术对小麦品质的影响[J].中国粮油学报,2015(1):107-111.
[5] 葛蒙蒙,马涛,陈家豪.绿色储粮技术及其使用效果分析[J].粮食科技与经济,2019(1):53-55.
[6] 张敏,周凤英.粮食储藏学[M].北京:科学出版社,2010:229-232.
[7] 张振军,曹阳,李建智,等.食品级惰性粉内环流施用研究[J].河南工业大学学报:自然科学版,2019,40(3):1-5.
[8] MEWIS I,ULRICHS C.Action of amorphous diatomaceous earth against different stages of the stored product pests Tribolium confusum,Tenebrio molitor,Sitophilus granarius and Plodia interpunctella[J].Journal of Stored Products Research,2001,37(2):153-164.
[9] 国家粮食局.LS/T 1201—2002磷化氢环流熏蒸技术规程[S].北京:中国标准出版社,2002:3.
[10] XUE Jun,ZHOU Lin-li,LIU Lei,et al.Control system of grain circulation fumigation based on agent[J].Scientific Journal of Control Engineering,2017(1):1-8.
[11] 白旭光.储粮物害虫与防治[M].北京:科学出版社,2008.
[12] 龚镇.化工百科全书[M].北京:化学工业出版社,1996:436-437.
[13] HORN P.Control of Brevipalpus chilensis with phosphine on fresh fruits under cold storage fumigations[C]//NAVARRO S,BANKS H J,JAYAS D S,et al.Proceedings of 9th International Conference of Atmosphere and Fumigation in Stored Products 15-19 October 2012,Antalya,Turkey.Turkey:[s.n.],2012:231-235.
[14] NAYAK M K,HOLLOWAY J C,PAVIC H,et al.Developing strategies to manage highly phosphine resistant populations of flat grain beetles in large bulk storages in Australia[C]//CARVALHO M O,FIELDS P G,ADLER C S,et al.Proceedings of the 10th International Working Conference on Stored Product Protection 27 June to 2 July 2010,Estoril,Portugal.Berlin:[s.n.],2010:396-401.
[15] 谢俭波,李长升,王永利.四种熏蒸剂杀虫灭鼠效果评价[J].医学动物防制,2003,19(3):157-160.
[16] MELNICK R L,SILLS R C.Comparative carcinogenicity of 1,3-butadiene,isoprene,and chloroprene in rats and mice[J].Chemico-biological interactions,2001,135:27-42.
[17] 中华人民共和国卫生部.GBZ 2.1—2007 工业场所有害因素职业接触限值第1部分:化学有害因素[S].北京:人民卫生出版社,2007:7.
[18] 黄建国,白旭光.农户储粮百问百答[M].北京:中国农业出版社,1999:94-102.
[19] GREENBERG J O.The neurological effects of methyl bromide Poisoning[J].Ind Med Surg,1971,40(4):27.
[20] 严晓平,穆振亚,李丹丹,等.硫酰氟防治储粮害虫研究和应用进展[J].粮食储藏,2018,47(4):15-19.
[21] 姚松银,黄谊,段丽琼,等.复方熏蒸剂杀菌杀虫效果研究[J].中华卫生杀虫药械,2011,17(5):356-359.
[22] 余琼粉,易红宏,唐晓龙,等.磷化氢净化技术及其展望[J].环境科学与技术,2009,32(10):87-91,132.
[23] COLABELLA J M,STALL R A,SORENSON C T.The adsorption and subsequent oxidation of AsH3 and PH3 on activated carbon[J].Journal of Crystal Growth,1988,92(1/2):189-195.
[24] 高红,张永,宁平,等.金属改性碳脱除PH3和H2S动力学及反应机理研究[J].环境工程学报,2009,3(2):301-305.
[25] LI Shan,HAO Ji-ming,NING Ping,et al.Preparation of Cu-Fe nanocomposites loaded diatomite and their excellent performance in simultaneous adsorption/oxidation of hydrogen sulfide and phosphine at low temperature[J].Separation and Purification Technology,2017,180(1):23-35.
[26] YU Qiong-fen,NING Ping,YI Hong-hong,et al.Effect of preparation conditions on the property Cu/AC adsorbents for phosphine adsorption[J].Separation Science and Technology,2012,47(3):527-533.
[27] 蒋明,宁平,徐浩东,等.改性活性炭吸附净化低浓度磷化氢[J].高校化学工程学报,2012(4):685-691.
[28] WANG Xue-qian,NING Ping,SHI Yun,et al.Adsorption of low concentration phosphine in yellow phosphorus off-gas by impregnated activated carbon[J].Journal of Hazardous Materials,2009,171(1/2/3):588-593.
[29] WILDE J.Absorbent mass for phosphine:Internationale veraffentli-chungsnummer,WO 00/21644 A3[P].2000-04-20.
[30] 李云玲,黄健翔.催化氧化活性炭法净化磷化氢熏蒸尾气综述[J].环保科技,2016,22(4):62-64.
[31] XU Xuan-wen,HUANG Guo-qiang,QI Shuai.Properties of AC and 13X zeolite modified with CuCl₂,and Cu(NO₃)₂,in phosphine removal and the adsorptive mechanisms[J].Chemical Engineering Journal,2017,316:563-572.
[32] QU Guang-fei,ZHANG Jian,LIN Yi-lu,et al.Electrochemical method for wet removal of phosphine[J].Environmental Progress & Sustainable Energy,2015,34(6):1 640-1 646.
[33] HERMAN T,SODEN S.Efficieny handling effluent gases through chemical scrubbing[C]//WERNER Luft.AIP Conference Proceedings 19-20 January 1988,Denver,CO,USA.New York:[s.n.],1988:99-108.
[34] CHANDRASEKARAN K,SHARMA M M.Absorption of phosphine in aqueous solutions of sodium hypochlorite and sulphuric acid[J].Chemical Engineering Science,1977,32(3):275-280.
[35] DENG Jing,CHEN Liang,WEI Wen.The study on removal the PH₃ in CO by dephosphorization bacteria[J].Advanced Materials Research,2013,781/782/783/784:861-868.
[36] 王瑾丰,牛晓君,马金玲,等.厌氧条件下微生物将磷还原为磷化氢[J].微生物学通报,2015,42(1):34-41.
[37] 肖瑢,刘树根,杨希,等.活性污泥体系中磷化氢生物降解特性[J].环境工程学报,2018,12(3):855-862.
[38] 刘树根,苏福家,李婷,等.生物滴滤法净化低浓度磷化氢及其微生物群落分析[J].环境工程学报,2018,12(12):124-132.
[39] BURROWS H D,CANLE L M,SANTABALLA J A,et al.Reaction pathways and mechanisms of photodegradation of pesticides[J].Journal of Photochemistry and Photobiology B Biology,2002,67(2):71-108.
[40] 王殿轩,冷本好,安西友,等.光源及温湿度条件对磷化氢光降解的影响[J].植物检疫,2013,27(5):45-49.
[41] 马梦苹,尹绍东,张来林,等.不同条件对臭氧紫外灯降解粮库磷化氢熏蒸尾气速率的影响[J].粮食与饲料工业,2015(9):17-20.
[42] 许根慧,姜恩永,盛京.等离子体技术与应用[M].北京:化学工业出版社,2006:2.
[43] 陈鹏,陶雷,谢怡冰,等.低温等离子体协同催化降解挥发性有机物的研究进展[J].化工进展,2019,38(9):4 284-4 294.
[44] KRUGLY E,MARTUZEVICIUS D,TICHONOVAS M,et al.Decomposition of 2-naphthol in water using a non-thermal plasma reactor[J].Chemical Engineering Journal,2015,260:188-198.
[45] ATKINSON R.Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions[J].Chemical Reviews,1986,86(1):69-201.
[46] 王保伟,姚淑美,彭叶平,等.介质阻挡放电等离子体降解高浓度甲苯[J].环境工程学报,2018,12(7):1 977-1 985.
[47] KUROKI T,OISHI T,YAMAMOTO T,et al.Bromomethane decomposition using a pulsed dielectric barrier discharge[J].IEEE Transactions on Industry Applications,2013,49(1):293-297.
[48] 李战国,胡真,闫学锋,等.低温等离子体治理H2S污染的实验研究[J].环境工程学报,2006,7(10):106-108.
[49] 张硕,梁旭,于欣扬,等.低温等离子体协同催化技术降解VOCs现状[J].环境保护与循环经济,2019,39(2):22-26,70.
[50] ZHU Xin-bo,GAO Xiang,QIN Rui,et al.Plasma-catalytic removal of formaldehyde over Cu-Ce catalysts in a dielectric barrier discharge reactor[J].Applied Catalysis B:Environmental,2015,170/171:293-300.
[51] SONG Hua,HU Fang-yun,PENG Yue,et al.Non-thermal plasma catalysis for chlorobenzene removal over CoMn/TiO₂,and CeMn/TiO₂:Synergistic effect of chemical catalysis and dielectric constant[J].Chemical Engineering Journal,2018,347:447-454.
[52] LEE B Y,PARK S H,LEE S C,et al.Decomposition of benzene by using a discharge plasma-photocatalyst hybrid system[J].Catalysis Today,2004,93(9):769-776.
[53] JURGEN M,MARTIN S,RAFL S,et al.Nonthermal plasma chemistry and physics[M].New York:CRC Press,2013:128.
[54] 马懿星.电晕放电协同分离转化黄磷炉气中粉尘和磷硫杂质[D].昆明:昆明理工大学,2016:47-56.
[55] LU Wen-jing,ABBAS Y,MUSTAFA M F,et al.A review on application of dielectric barrier discharge plasma technology on the abatement of volatile organic compounds[J].Frontiers of Environmental Science & Engineering,2019,13(2):30.
[56] DU Chang-ming,HUANG Ya-ni,GONG Xiang-jie,et al.Plasma purification of halogen volatile organic compounds[J].IEEE Transactions on Plasma Science,2018,46(4):838-858.