Abstract
Objective: A new type of static mixer to enhance the ozone gas-liquid phase mass transfer was established in this study. Methods: The effects of different ozone gas flow rates, liquid flow rates and liquid temperature on the concentration of ozone liquid phase and the generation of hydroxyl radicals were investigated, and were compared with the microporous aeration method and the circulating jet method. Results: With the increase of the gas-liquid flow rate, the ozone water saturation concentration and the hydroxyl radical concentration both increased; as the temperature increased, the ozone water saturation concentration decreased, but the hydroxyl radical concentration increased. With the gas flow rate at 2, the liquid flow rate at 12 L/min and the liquid temperature at 10 ℃, the saturated concentration of ozone water reached 12.67 mg/L, and the concentration of hydroxyl radicals in ozone water was 85.11 μmol/L. The output of hydroxyl radicals was higher than that of microporous exposure. The air method and the circulating jet method increased by 73.4% and 20.6%, respectively. Conclusion: The new static mixer has a significant strengthening effect on the ozone-water liquid phase mass transfer and the generation of hydroxyl radicals.
Publication Date
11-28-2021
First Page
1
Last Page
5,240
DOI
10.13652/j.issn.1003-5788.2021.11.001
Recommended Citation
Xin-yu, LIU; Bo-wen, ZHANG; and Zheng-wei, CUI
(2021)
"Enhancing hydroxyl radical production in ozone water by new type static mixer,"
Food and Machinery: Vol. 37:
Iss.
11, Article 1.
DOI: 10.13652/j.issn.1003-5788.2021.11.001
Available at:
https://www.ifoodmm.cn/journal/vol37/iss11/1
References
[1] WYSOK B, URADZINSKI J, GOMOLKAPAWLICKA M. Ozone as an alternative disinfectant[J]. Polish Journal of Food & Nutrition Sciences, 2006, 15(56): 3-8.
[2] 袁成豪, 刘永乐, 黄轶群, 等. 臭氧冰制备技术及其在食品保鲜中的应用研究进展[J]. 食品与机械, 2019, 35(5): 224-230.
[3] HOIGNE J, BADER H. Rate constants of reactions of ozone with organic and inorganic compounds in water III: Inorganiccompounds and radicals[J]. Water Research, 1983, 19(2): 993-1 004.
[4] GAO Mei-ping, ZENG Ze-quan, SUN Bao-chang, et al. Ozonation of azo dye acid red 14 in a microporous tube-in-tube microchannel reactor: decolorization andmechanism[J]. Chemosphere, 2012, 89(2): 190-197.
[5] 秦月娇, 焦纬洲, 杨鹏飞, 等. 强化臭氧传质的研究进展[J]. 过程工程学报, 2017, 17(2): 420-426.
[6] 曾尚升, 杨宇成, 张娜, 等. 旋转微气泡反应器强化臭氧降解水中对硝基苯酚[J]. 化工进展, 2021, 40(7): 4 091-4 099.
[7] 李森, 尚凯, 李璐, 等. 高密度羟自由基生成技术的研究[J]. 当代化工, 2019, 48(5): 961-965.
[8] ROSENFELDT E J, LINDEN K G, CANONICA S, et al. Comparison of the efficiency of ·OH radical formation during ozonation and the advanced oxidation processes O3/H2O2 and UV/H2O2[J]. Water Research, 2006, 40(20): 3 695-3 704.
[9] HE Zhi-qiao, LIN Li-li, SONG Shuang, et al. Mineralization of CI reactive blue 19 by ozonation combined with sonolysis: Performance optimization and degradation mechanism[J]. Separation and Purification Technology, 2008, 62(2): 376-381.
[10] ZCAN A, 瘙塁AHIN Y, KOPARAL A S, et al. Carbon sponge as a new cathode material for the electro-Fenton process: Comparison with carbon felt cathode and application to degradation of synthetic dye basic blue 3 in aqueous medium[J]. Journal of Electroanalytical Chemistry, 2008, 616(S1/S2): 71-78.
[11] 熊鑫高原. 超声强化臭氧传质与自由基形成机制研究[D]. 成都: 西南石油大学, 2019: 56-60.
[12] WANG Wan-ting, FAN Wei, HUO Ming-xin, et al. Hydroxyl radical generation and contaminant removal from water by the collapse of microbubbles under different hydrochemical conditions[J]. Water, Air and Soil Pollution, 2018, 229(86): 2-11.
[13] 蒋丽春, 唐绍明, 游青, 等. 靛蓝二磺酸钠褪色分光光度法测定水中臭氧[J]. 理化检验(化学分册), 2011, 47(2): 180-182.
[14] MILAN-SVIAEGO N, WANG Y, CANNON F S, et al. Comparison of hydroxyl radical generation for various advanced oxidation combinations as applied to foundries[J]. Ozone: Science and Engineering, 2007, 29(6): 461-471.
[15] 吴春笃, 张波, 储金宇, 等. 一种羟基自由基浓度的测定方法: 200810019693.3[P]. 2008-08-13.
[16] FANG X, MARK G, SONNTAG C V. OH radical formation by ultrasound in aqueous solutions Part I: The chemistry underlying the terephthalate dosimeter[J]. Ultrasonics Sonochemistry, 1996, 3(1): 57-63.
[17] MILLER C J, ROSE A L, WAITE T D. Phthalhydrazide chemiluminescence method for determination of hydroxyl radical production: Modifications and adaptations for use in natural systems[J]. Analytical Chemistry, 2011, 83(1): 261-268.
[18] YILDIRIM A, BALCI M A. Analytical solution for the mass transfer of ozone of the second order from gaseous phase to aqueous phase[J]. Asian Journal of Chemistry, 2011, 23(9): 3 795-3 798.
[19] MILNE L, STEWART I, BREMNER D H. Comparison of hydroxyl radical formation in aqueous solutions atdifferent ultrasound frequencies and powers using the salicylic acid dosimeter[J]. Ultrasonics Sonochemistry, 2013, 20(3): 984-989.