Abstract
Objective: Studied the adsorption characteristics of magnetic chitosan modified kaolin on caffeic acid in simulated sugarcane juice, and provided the reference for the removal of phenolic pigments in sugarcane juice. Methods: Magnetic chitosan modified kaolin was prepared by coprecipitation of chitosan, nano ferric oxide and kaolin. The surface structure and group changes of kaolin before and after modification were characterized by FT-IR, VSM and SEM; The adsorption characteristics of caffeic acid were studied by adsorption test. Results: the modified chitosan and nano-Fe3O4 were successfully loaded on kaolin, and the adsorption performance of caffeic acid was improved. The isoelectric point of magnetic chitosan modified kaolin was 4.54, and the acid condition was conducive to the removal of caffeic acid, and the adsorption equilibrium was reached at 240 min. The adsorption process of caffeic acid on magnetic chitosan modified kaolin was more consistent with the pseudo second order kinetics and Langmuir isotherm adsorption model. The adsorption process was mainly chemical adsorption and monolayer adsorption. The thermodynamic study showed that the adsorption process was spontaneous endothermic process. Conclusion: Magnetic chitosan modified kaolin exhibited strong adsorption capacity for caffeic acid in sugarcane juice, and can be used as sugar clarifier for the adsorption of caffeic acid in sugarcane juice.
Publication Date
8-28-2021
First Page
33
Last Page
39
DOI
10.13652/j.issn.1003-5788.2021.08.005
Recommended Citation
Yan-mei, PAN; Hai-ling, WU; Qiao-yan, WEI; Long, SU; and Fu-jie, LIU
(2021)
"Adsorption of caffeic acid in sucrose solution by magnetic chitosan modified kaolin,"
Food and Machinery: Vol. 37:
Iss.
8, Article 5.
DOI: 10.13652/j.issn.1003-5788.2021.08.005
Available at:
https://www.ifoodmm.cn/journal/vol37/iss8/5
References
[1] 范晓航. 蔗糖产业发展新模式探索[D]. 南宁: 广西大学, 2020: 1-2.
[2] SONG Xiao-rong, CHAI Zhi-hui, ZHU Yuan, et al. Preparation and characterization of magnetic chitosan-modified diatomite for the removal of gallic acid and caffeic acid from sugar solution[J]. Carbohydrate Polymers, 2019, 219: 316-327.
[3] 柴智慧. 精氨酸改性磁性壳聚糖糖用澄清剂的制备及其应用工艺研究[D]. 南宁: 广西大学, 2020: 3-4.
[4] FAN Song-lin, HUANG Zu-qiang, ZHANG Yan-juan, et al. Magnetic chitosan-hydroxyapatite composite microspheres: Preparation, characterization, and application for the adsorption of phenolic substances[J]. Bioresource Technology, 2019, 274: 48-55.
[5] 任勤. 壳聚糖磷酸酯糖用澄清剂的制备及其应用工艺研究[D]. 南宁: 广西大学, 2017: 1-3.
[6] SOUZA J A, CLIO F F A, MARCOS N E, et al. Criegee mechanism as a safe pathway of color reduction in sugarcane juice by ozonation[J]. Food Chemistry, 2017, 225: 181-187.
[7] SUSANTO H, ROIHATIN A,WIDIASA I N. Production of colorless liquid sugar by ultrafiltration coupled with ion exchange[J]. Food and Bioproducts Processing, 2016, 98: 11-12.
[8] 曲睿晶, 宋颖雪, 兰梅娟, 等. 陶瓷膜分离技术在制糖工业中的研究应用[J]. 中国调味品, 2017, 42(6): 72-76.
[9] 卞晓彤, 邱兆富, 杨骥, 等. 海藻酸钠/氢氧化镧改性Y型分子筛颗粒除氟研究[J]. 无机盐工业, 2020, 52(12): 86-91.
[10] THAGIRA B H, KARTHIKEYAN P, MEENAKSHI S. Lanthanum(III) encapsulated chitosan-montmorillonite composite for the adsorptive removal of phosphate ions from aqueous solution[J]. International Journal of Biological Macromolecules, 2018, 112: 284-293.
[11] LIU Dong-mei, CHEN Dong, ZHONG Jing-ping, et al. Facile preparation of chitosan modified magnetic kaolin by one-pot coprecipitation method for efficient removal of methyl orange[J]. Carbohydrate Polymers, 2020, 245: 1-32.
[12] MOUNI L, BELKHIRI L, BOLLINGER J C, et al. Removal of methylene blue from aqueous solutions by adsorption on kaolin: Kinetic and equilibrium studies[J]. Applied Clay Science, 2018, 153: 38-45.
[13] 李文斌. 两性—阴(阳)离子复配修饰黏土的修饰机制及其对菲、Cr(Ⅵ)的吸附[D]. 咸阳: 西北农林科技大学, 2016: 3-5.
[14] ZHAO Zhen-gang, YU Shu-juan, XIONG Fu, et al. Simultaneous determination of ten major phenolic acids in sugarcane by a reversed phase HPLC method[J]. Sugar Industry, 2008, 133(8): 503-507.
[15] 牛三鑫, 谢晓康, 王正, 等. 壳聚糖包覆高岭土对刚果红吸附性能研究[J]. 应用化工, 2020, 49(5): 1 156-1 159.
[16] SETHY T R, SAHOO P K. Highly toxic Cr (VI) adsorption by (chitosan-g-PMMA)/silica bionanocomposite prepared via emulsifier-free emulsion polymerisation[J]. International Journal of Biological Macromolecules, 2019, 122: 1 184-1 190.
[17] TANHAEI B, AYATI A, LAHTINEN M, et al. Preparation and characterization of a novel chitosan/Al2O3/magnetite nanoparticles composite adsorbent for kinetic, thermodynamic and isotherm studies of methyl orange adsorption[J]. Chemical Engineering Journal, 2015, 259: 1-10.
[18] LEI Chun-feng, ZHU Xiao-feng, ZHU Bi-chen, et al. Superb adsorption capacity of hierarchical calcined Ni/Mg/Al layered double hydroxides for Congo red and Cr(VI) ions[J]. Journal of Hazardous Materials, 2017, 321: 801-811.
[19] 郑宁捷. 锆铁改性芦苇生物炭吸附水体中磷的研究[D]. 南京: 南京信息工程大学, 2018: 16-17.
[20] BELVER C, VICENTE M A. Chemical activation of a kaolinite under acid and alkaline conditions[J]. Chemistry of Materials, 2002, 14(5): 2 033-2 043.
[21] LI Gui-yin, JIANG Yu-ren, HUANG Ke-long, et al. Preparation and properties of magnetic Fe3O4-chitosan nanoparticles[J]. Journal of Alloys & Compounds, 2008, 466: 451-456.
[22] 于长江, 王苗, 董心雨, 等. 海藻酸钙@Fe3O4/生物碳磁性复合材料的制备及其对Co(Ⅱ)的吸附性能和机制[J]. 复合材料学报, 2018, 35(6): 1 549-1 557.
[23] EROL A, AY瘙塁EGL M, FRANCOIS B. Methylene blue adsorption on magnetic alginate/rice husk bio-composite[J]. International Journal of Biological Macromolecules, 2020, 154: 104-113.
[24] XING Rong-rong, HU Shuang, CHEN Xuan, et al. Graphene sensitized microporous membrane/solvent microextraction for the preconcentration of cinnamic acid derivatives in Rhizoma Typhonii[J]. Journal of Separation Science, 2014, 37(17): 2 307-2 313.
[25] 阳晶, 李忠海. Fe3O4@VC磁性纳米粒子对Cr(Ⅵ)的吸附性能[J]. 食品与机械, 2017, 33(4): 75-80.
[26] XUE Ai-lian, ZHOU Shou-yong, ZHAO Xiao-ping, et al. Effective NH2-grafting on attapulgite surfaces for adsorption of reactive dyes[J]. Journal of Hazardous Materials, 2011, 194: 7-11.
[27] 李丰泉, 曾凡坤, 钟金锋, 等. 辣木籽壳对亚甲基蓝的吸附特性[J]. 食品与机械, 2019, 35(1): 63-68.
[28] 郑迎莹, 王大红, 徐鹏, 等. 纳他霉素的大孔树脂原位吸附动力学研究[J]. 食品与机械, 2019, 35(12): 42-46.
[29] 徐颖, 李洁, 贺丹丹, 等. 两株乳酸菌对铅的吸附作用[J]. 食品与机械, 2018, 34(3): 49-53.
[30] ZENG Guang-ming, LIU Yuan-yuan, LIN Tang, et al. Enhancement of Cd(II) adsorption by polyacrylic acid modified magnetic mesoporous carbon[J]. Chemical Engineering Journal, 2015, 259: 153-160.
[31] 姜侠, 王冠, 刘振华, 等. 改性活性炭对亚甲基蓝的吸附性能及机理[J]. 水处理技术, 2020, 46(6): 76-82.
[32] LEITE A J B, SOPHIA C A, THUE P S, et al. Activated carbon from avocado seeds for the removal of phenolic compounds from aqueous solutions[J]. Desalination and Water Treatment, 2017, 71(4): 168-181.