Abstract
Objective: This study aimed to rapidly detect the residual quantity of thiamendazole in food. Methods: O-aminophenol and o-phenylenediamine were screened as composite functional monomers by ultraviolet spectroscopy. The polymerization and elution conditions were studied by electrochemical analysis, and the performance of the sensor was evaluated. A rapid method for the determination of thiamendam residues in food was established. Results: Under the control of the optimal conditions, the imprinted sensor had the specific adsorption performance for thiamendam and its structural analogues, and the selectivity for thiamendam was the strongest. The linear relationship of this method ranged from 1.0×10-8 to 1.0×10-4 mol/L, and the detection limit was 3.3×10-9 mol/L; The average recoveries of the spiked samples were 88.16%~100.73%, and the relative standard deviations were less than 2.63%. Conclusion: The sensor has excellent imprinting effect, selectivity, reproducibility and stability, and can be used for the rapid detection of thiamendam residues in food.
Publication Date
4-25-2023
First Page
55
Last Page
60,232
DOI
10.13652/j.spjx.1003.5788.2022.80720
Recommended Citation
Xiao-ting, YOU; Jing, HU; Dong-dong, ZHANG; Lu-hua, TANG; and Wen-hui, GAO
(2023)
"Preparation and application of thiabendazole molecularly imprinted sensor based on composite functional monomers,"
Food and Machinery: Vol. 39:
Iss.
3, Article 10.
DOI: 10.13652/j.spjx.1003.5788.2022.80720
Available at:
https://www.ifoodmm.cn/journal/vol39/iss3/10
References
[1] 曹雪琴, 杨飞, 陈国通, 等. 超高效液相色谱—串联质谱法同时测定水果中10种保鲜剂残留量[J]. 食品科学, 2020, 41(4): 319-324.
[2] DONG Y Y, YANG L J, ZHANG L. Simultaneous electrochemical detection of benzimidazole fungicides carbendazim and thiabendazole using a novel nanohybrid material-modified electrode[J]. J Agric Food Chem, 2017, 65(4): 727-736.
[3] 杨续金, 王东清, 任俌政, 等. 液相微萃取法快速检测果蔬中噻菌灵残留量[J]. 食品工业, 2021, 42(7): 292-296.
[4] 陈丽霞, 许丽建. 动物源食品中噻菌灵残留分析的净化方法比较[J]. 食品与发酵工业, 2020, 46(24): 218-223.
[5] FENG J Y, HU Y X, GRANT E, et al. Determination of thiabendazole in orange juice using an MISPE-SERS chemosensor[J]. Food Chemistry, 2018, 239: 816-822.
[6] 李涛, 李文辉, 李俊毅, 等. HPLC测定菠萝汁中多菌灵、噻菌灵和甲基硫菌灵[J]. 食品工业, 2017, 38(4): 289-291.
[7] 李青龙, 王利华, 钟跃汉, 等. 表面增强拉曼光谱法快速检测香蕉中的噻菌灵[J]. 光谱学与光谱分析, 2018, 38(1): 135-136.
[8] ROMERO-CANO R, DIEGO K, PERIS-VICENTE J, et al. Analysis of thiabendazole, 4-tert-octylphenol and chlorpyrifos in waste and sewage water by direct injection-micellar liquid chromatography[J]. Analyst, 2015, 140(5): 1 739-1 746.
[9] 孙海博, 吴海龙, 陈安祺, 等. 三维荧光结合化学多维校正快速灵敏测定环境水样中的噻菌灵和双酚A[J]. 光谱学与光谱分析, 2021, 41(8): 2 511-2 517.
[10] 周冰, 安国荣, 朱琳, 等. LC-MS/MS法检测樱桃和土壤中抗灰霉病农药残留[J]. 中国测试, 2022, 48(2): 80-85.
[11] 杨丽芬, 杨忠平, 邵林, 等. QuEChERS-高效液相色谱法测定苹果中多菌灵和噻菌灵[J]. 食品安全质量检测学报, 2020, 11(7): 2 257-2 262.
[12] ZHU S S, GAO M, TIAN S, et al. Simultaneous determination of 19 antibiotics and 19 anthelmintics residues in edible fungi by UHPLC-MS/MS in combination with QuEChERS method[J]. Food Analytical Methods, 2021, 14(6): 1 278-1 288.
[13] OLIVEIRA M, RUBIRA R, FURINIL N, et al. Detection of thiabendazole fungicide/parasiticide by SERS: Quantitative analysis and adsorption mechanism[J]. Applied Surface Science, 2020, 517: 1-29.
[14] 刘霄希. 基于柔性材料和SERS技术的番茄表面农药残留快速检测的研究[D]. 杭州: 浙江大学, 2021: 50-51.
[15] 占绣萍, 刘彬, 黄兰淇, 等. 应用胶体金法检测叶类蔬菜中吡虫啉、多菌灵、啶虫脒、噻虫嗪的残留量分析[J]. 农药科学与管理, 2021, 42(10): 24-31.
[16] WANG M S, ZHU W B, ZHAO L Y, et al. Simultaneous detection of thiabendazole and carbendazim in foods based on two-color up conversion and magnetic separation nanoparticles fluorescence immunoassay[J]. European Food Research and Technology, 2021, 248(1): 85-94.
[17] LI J, MA X G, ZHANG M Y, et al. Preparation of molecularly imprinted polymer sensor on electrochemically reduced graphene oxide modified electrode for selective probing of thiabendazole[J]. Journal of The Electrochemical Society, 2019, 166(2): 84-91.
[18] 唐录华, 秦思楠, 高林, 等. 基于对巯基苯胺膜的高灵敏己烯雌酚印迹传感器的制备及应用[J]. 化工进展, 2019, 38(11): 5 074-5 083.