•  
  •  
 

Corresponding Author(s)

方芳(1979—),男,长沙理工大学副教授,博士。E-mail:lgdx08@sina.com

Abstract

Objective: To establish a rapid qualitative and quantitative method for the adulteration of Camellia seed oil. Methods: The electronic nose technology combined with chemometrics was used to screen the difference variables based on one-way ANOVA. The qualitative model for identification of adulteration types of camellia seed oil was established through principal component analysis (PCA) and discriminant analysis (DA). A quantitative model for identifying the types and degrees of camellia seed oil adulteration was established using orthogonal partial least squares (OPLS). Results: The R2 of the model was over 0.98, the RMSEE was lower than 0.005, and the RMSECV was lower than 0.01, which had the high performance indicators. Through external verification, the qualitative identification rate of DA model for camellia seed oil samples of different adulteration types was as high as 100%, and OPLS model had good accuracy. Conclusion: The electronic nose technology combined with chemometrics could realize the rapid and nondestructive identification of camellia seed oil adulteration.

Publication Date

10-20-2023

First Page

31

Last Page

36,179

DOI

10.13652/j.spjx.1003.5788.2022.81169

References

[1] 陈则铭, 赵鑫鑫, 朱晓阳, 等. 基于浸出茶油香气成分压榨茶油掺伪模型及应用[J]. 食品与机械, 2022, 38(3): 51-59, 102. CHEN Z M, ZHAO X X, ZHU X Y, et al. Adulteration model establishment of camellia oil based on aroma components extracted from camellia oil and its application[J]. Food & Machinery, 2022, 38(3): 51-59, 102.
[2] 王铮, 曹清明, 裴小芳, 等. 在油茶籽油国家标准中增设脂质伴随物营养声称指标的可行性研究[J]. 食品与机械, 2021, 37(9): 8-14, 22. WANG Z, CAO Q M, PEI X F, et al. Feasibility study on developing nutrient claim of lipid concomitants in national standard of oil-tea camellia seed oil[J]. Food & Machinery, 2021, 37(9): 8-14, 22.
[3] 孙婷婷, 陈志清, 钟瑾璟, 等. 基于挥发性成分定量预测风味茶油掺浸出茶油的偏最小二乘回归模型的建立[J]. 中国粮油学报, 2022, 37(12): 251-258. SUN T T, CHEN Z Q, ZHONG J J, et al. Establishment of partial least squares regression model forquantitative prediction of flavor camellia oil adulterated with extracted camellia oil based on volatile components[J]. Journal of the Chinese Cereals and Oils Association, 2022, 37(12): 251-258.
[4] HUANG C Q, GU Y. A machine learning method for the quantitative detection of adulterated meat using a MOS-based e-nose[J]. Foods, 2022, 11(4): 602.
[5] 刘晓华, 范三红, 马俪珍, 等. 利用Flash E-Nose方法探究漂洗处理对鲶鱼鱼糜的脱腥效果[J]. 食品科学, 2015, 36(2): 132-136. LIU X H, FAN S H, MA L Z, et al. Evaluation of rinsing for deodorization of catfish surimi by flash e-nose[J]. Food Science, 2015, 36(2): 132-136.
[6] SONG J X, CHEN Q Q, BI J F, et al. GC/MS coupled with MOS e-nose and flash GC e-nose for volatile characterization of Chinese jujubes as affected by different drying methods[J]. Food Chemistry, 2020, 331: 127201.
[7] HE J H, WU X H, YU Z L. Microwave pretreatment of camellia (Camellia oleifera Abel.) seeds: Effect on oil flavor[J]. Food Chemistry, 2021, 364: 130388.
[8] SHI J, NIAN Y Q, DA D D, et al. Characterization of flavor volatile compounds in sauce spareribs by gas chromatography-mass spectrometry and electronic nose[J]. LWT, 2020, 124: 109182.
[9] 吴嘉雯, 刘智昊, 庞林江, 等. 电子鼻技术在果蔬病害检测中的研究进展[J]. 食品与机械, 2023, 39(1): 228-233. WU J W, LIU Z H, PANG L J, et al. Research progress of electronic nose in fruit and vegetable disease detection[J]. Food & Machinery, 2023, 39(1): 228-233.
[10] 郭永跃, 马君义, 吕孝飞, 等. 基于电子鼻技术鉴别陇南初榨橄榄油[J]. 中国粮油学报, 2021, 36(8): 94-100. GUO Y Y, MA J Y, LU X F, et al. Identification of Longnan virgin olive oil based on electronic nose technology[J]. Journal of the Chinese Cereals and Oils Association, 2021, 36(8): 94-100.
[11] 任敏, 多拉娜, 王帅, 等. 基于电子鼻和电子舌技术评价乳酸乳球菌对发酵乳风味品质的影响[J]. 中国食品学报, 2021, 21(1): 246-255. REN M, DUO L N, WANG S, et al. Effect of Lactococcus lactis on flavor quality of fermented milk based on electronic tongue and electronic nose[J]. Journal of Chinese Institute of Food Science and Technology, 2021, 21(1): 246-255.
[12] 彭星星, 陈文敏, 罗仁仙, 等. 电子鼻鉴别核桃油中掺入大豆油、菜籽油及玉米油研究[J]. 中国粮油学报, 2015, 30(11): 129-134. PENG X X, CHEN W M, LUO R X, et al. Detection of walnut oil adulterated with soybean rape seed oil/corn oil using electronic nose[J]. Journal of the Chinese Cereals and Oils Association, 2015, 30(11): 129-134.
[13] ZHANG M N, LI L Q, SONG G S, et al. Analysis of volatile compound change in tuna oil during storage using a laser irradiation based HS-SPME-GC/MS[J]. LWT, 2020, 120: 108922.
[14] ZHU W H, LUAN H W, BU Y, et al. Flavor characteristics of shrimp sauces with different fermentation and storage time[J]. LWT, 2019, 110: 142-151.
[15] WANG Q, LI L, DING W, et al. Adulterant identification in mutton by electronic nose and gas chromatography-mass spectrometer[J]. Food Control, 2018, 98: 431-438.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.