Determination of chlorantraniliprole and penoxsulam residues in rice by QuEChERS-UPLC-MS/MS

Authors

HUANG Zijie, Huaihua Center for Disease Control and Prevention, Huaihua, Hunan 418000, China
HUANG Pengmian, Huaihua Center for Disease Control and Prevention, Huaihua, Hunan 418000, ChinaFollow
LUO Kuanneng, School of Chemistry and Chemical Engineering, Changsha University of Science & Technology, Changsha, Hunan 410114, China
XIANG Zhongping, School of Chemistry and Chemical Engineering, Changsha University of Science & Technology, Changsha, Hunan 410114, China
ZHANG Honggang, School of Chemistry and Chemical Engineering, Changsha University of Science & Technology, Changsha, Hunan 410114, China

Corresponding Author(s)

黄朋勉（1972—），男，长沙理工大学副教授，博士。E-mail：huangpengmian@126.com

Abstract

Objective: To establish a new QuEChERS-ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method for the detection of chlorantraniliprole and penoxsulam residues in rice. Methods: After the sample was extracted with 0.2% formic acid-acetonitrile, purified with N-propylethylenediamine (PSA) and graphitized carbon black (GCB) packing, 0.2% formic acid water and acetonitrile were used as mobile phases for gradient elution, and then subjected to C₁₈ chromatography. UPLC-MS/MS was used to column separation and determination. Results: The limits of quantification (LOQ) of chlorantraniliprole and penoxsulam were both 0.004 mg/kg, and the method detection limits (LOD) were both 0.001 mg/kg. Chlorantraniliprole and penoxsulam had a good linear relationship in the range of 0.002~0.5 mg/L, and their coefficient was greater than 0.993. At the addition levels of 0.05, 0.1, and 0.5 mg/kg, the average recovery rates of chlorantraniliprole and penoxsulam were 86% to 110% with the relative standard deviations (RSD) of 1.5% to 6.1%. Conclusion: This method is efficient and simple, has good stability and high sensitivity, and is suitable for the detection of chlorantraniliprole and penoxsulam in rice.

Publication Date

1-30-2024

First Page

63

Last Page

67

DOI

10.13652/j.spjx.1003.5788.2023.80822

Recommended Citation

Zijie, HUANG; Pengmian, HUANG; Kuanneng, LUO; Zhongping, XIANG; and Honggang, ZHANG (2024) "Determination of chlorantraniliprole and penoxsulam residues in rice by QuEChERS-UPLC-MS/MS," Food and Machinery: Vol. 40: Iss. 1, Article 9.
DOI: 10.13652/j.spjx.1003.5788.2023.80822
Available at: https://www.ifoodmm.cn/journal/vol40/iss1/9

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