Abstract
Objective: This study aimed to optimize the aging technology of Fuyuxiangxing crude Baijiu and improve its quality. Methods: Testing and analyzing the new wine and the Fuyuxiangxing crude Baijiu aged for 1, 3, 5, 8 and 10 years allowed for the analysis of the physicochemical indexes such as pH, conductivity, viscosity, total acid and total ester. Additionally, the primary volatile flavor components of the six samples were qualitatively assessed using GC and GC-MS, and 26 volatile flavor components of the samples were quantitatively assessed using the external standard method. Results: With the increase of aging time, the conductivity increased, the viscosity increased, the total acid content increased and the total ester content decreased; 26 volatile flavor components were quantified in the 6 Fuyuxiangxing crude Baijiu, including 8 esters, 8 alcohols, 5 acids and 5 aldehydes and ketones, with the contents of esters increasing and then decreasing, the contents of alcohols showing a slow decreasing trend, and the contents of acids and aldehydes increasing. Both the principal component analysis (PCA) and the partial least squares discriminant analysis(PLS-DA) could better distinguish Fuyuxiangxing crude Baijiu with different aging time. Conclusion: The preliminary study reveals the changing rules of physicochemical properties and flavor substances during the aging process of Fuyuxiangxing crude Baijiu, and the appropriate aging time can improve the quality of crude Baijiu, which can provide a reference for the optimization of the aging technology of Fuyuxiangxing crude Baijiu.
Publication Date
7-22-2024
First Page
29
Last Page
36
DOI
10.13652/j.spjx.1003.5788.2024.80324
Recommended Citation
Mengsi, LU; Ji, YU; Bing, YU; Chaoyu, LIANG; and Maojun, YAO
(2024)
"Analysis of physical and chemical indicators and volatile composition changes during aging of Fuyuxiangxing crude Baijiu,"
Food and Machinery: Vol. 40:
Iss.
5, Article 4.
DOI: 10.13652/j.spjx.1003.5788.2024.80324
Available at:
https://www.ifoodmm.cn/journal/vol40/iss5/4
References
[1] 全国白酒标准化技术委员会. 白酒质量要求 第11部分: 馥郁香型白酒: GB/T 10781.11—2021[S]. 北京: 中国标准出版社, 2021: 3-5.
China National Committee for Standardization. Quality requirements for liquor, Part 11: Fuyuxiangxing Baijiu: GB/T 10781.11—2021[S]. Beijing: Standards Press of China, 2021: 3-5.
[2] 解成玉, 朱金玉, 李玉英. 白酒老熟技术及机理研究进展[J]. 酿酒科技, 2016(11): 95-96, 99.
XIE C Y, ZHU J Y, LI Y Y. Study of liquor aging technology and aging mechanism[J]. Liquor-Making Science & Technology, 2016(11): 95-96, 99.
[3] 曹敬华, 张明春, 朱正军, 等. 白云边酒陈酿过程理化指标变化规律探讨[J]. 中国酿造, 2017, 36(7): 67-70.
CAO J H, ZHANG M C, ZHU Z J, et al. Variation regularity of physicochemical indexes of Baiyunbian Baijiu during aging process[J]. China Brewing, 2017, 36(7): 67-70.
[4] XU M L, YU Y, RAMASWAMY H S, et al. Characterization of Chinese liquor aroma components during aging process and liquor age discrimination using gas chromatography combined with multivariable statistics[J]. Scientific Reports, 2017, 7(1): 39671.
[5] ZHAO D R, SHI D M, SUN J Y, et al. Characterization of key aroma compounds in Gujinggong Chinese Baijiu by gas chromatography-olfactometry, quantitative measurements, and sensory evaluation[J]. Food Research International, 2018, 105: 616-627.
[6] 胥佳, 何朝玖, 马浩, 等. 不同贮存年份的五粮浓香型白酒挥发性风味物质对比分析[J]. 食品与发酵科技, 2023, 59(3): 23-29.
XU J, HE C J, MA H, et al. Preliminary analysis of volatile flavor substances in Wuliang strong fragrant Baijiu of different storage years[J]. Food and Fermentation Technology, 2023, 59(3): 23-29.
[7] NIU Y W, CHEN X M, XIAO Z B, et al. Characterization of aroma-active compounds in three Chinese Moutai liquors by gas chromatography-olfactometry, gas chromatography-mass spectrometry and sensory evaluation[J]. Natural Product Research, 2016, 31(8): 938-944.
[8] 陈同强, 李灿, 王亮亮, 等. 不同酒龄馥郁香型白酒成分指标变化规律研究[J]. 食品安全质量检测学报, 2019, 10(6): 1 635-1 638.
CHEN T Q, LI C, WANG L L, et al. Change rules of ingredients of the heavy-flavor liquors with different ages[J]. Journal of Food Safety and Quality, 2019, 10(6): 1 635-1 638.
[9] 王金龙, 程平言, 陆伦维, 等. 基于DB-WAXUI色谱柱气相色谱法检测5种香型白酒中45种挥发性风味物质[J]. 中国酿造, 2023, 42(4): 238-243.
WANG J L, CHENG P Y, LU L W, et al. Detection of 45 volatile flavor compounds in 5 flavor types Baijiu by GC based on DB-WAX UI column[J]. China Brewing, 2023, 42(4): 238-243.
[10] 凌与听. 不同陈酿时间浓香型皖北名酒挥发性风味特征解析[D]. 无锡: 江南大学, 2022: 17-18.
LING Y T. Analysis of flavor characteristics in volatile compounds of strong-aroma type Baijiu from Wanbei region with different aging times[D]. Wuxi: Jiangnan University, 2022: 17-18.
[11] 何利, 廖永红, 陈波, 等. 不同酒瓶贮存酱香型白酒的酒体风味变化[J]. 酿酒科技, 2021(4): 61-64.
HE L, LIAO Y H, CHEN B, et al. Influence of different bottles on the flavor change of Jiangxiang Baijiu[J]. Liquor-Making Science & Technology, 2021(4): 61-64.
[12] 卢中明, 杜礼泉, 范昌明, 等. 不同陈酿方式对酒体主要金属元素含量及电导率变化规律的研究[J]. 酿酒, 2021, 48(4): 44-46.
LU Z M, DU L Q, FAN C M, et al. Study on the variation of metal content and electrical conductivity in base wine with different aging methods[J]. Liquor Making, 2021, 48(4): 44-46.
[13] 乔华, 马燕红, 赵振午, 等. 基于黏度研究清香型白酒中乙醇—水缔合行为[J]. 食品科学, 2011, 32(15): 14-19.
QIAO H, MA Y H, ZHAO Z W, et al. Investigation based on viscosity of the association behavior of ethanol and water in fen-flavor liquor[J]. Food Science, 2011, 32(15): 14-19.
[14] 乔华. 白酒陈化机理的研究及应用[D]. 太原: 山西大学, 2013: 59-91.
QIAO H. Maturation mechanism of Chinese distilled spirits and its application[D]. Taiyuan: Shanxi University, 2013: 59-91.
[15] XU Y Q, ZHAO J R, LIU X, et al. Flavor mystery of Chinese traditional fermented Baijiu: The great contribution of ester compounds[J]. Food Chemistry, 2022, 369: 130920.
[16] 孙细珍, 熊亚青, 刘家欢, 等. 清香型白酒新酒和陈酒感官特征及香气物质的差异性分析[J]. 食品科学, 2023, 44(14): 266-273.
SUN X Z, XIONG Y Q, LIU J H, et al. Difference analysis of sensory characteristics and aroma compounds between young and aged Qingxiangxing Baijiu[J]. Food Science, 2023, 44(14): 266-273.
[17] 徐志飞, 吴宇伉, 蒋瑜宏. 气相色谱质谱联用法测定白酒中4类风味物质[J]. 食品与机械, 2022, 38(11): 76-81, 124.
XU Z F, WU Y K, JIANG Y H. Determination of four flavor substances in Baijiu by gas chromatography-mass spectrometry[J]. Food & Machinery, 2022, 38(11): 76-81, 124.
[18] 范文来, 徐岩. 酒类风味化学[M]. 北京: 中国轻工业出版社, 2020: 168.
FAN W L, XU Y. Flavor chemistry of alcoholic beverage[M]. Beijing: China Light Industry Press, 2020: 168.
[19] 黄琴, 陈茂彬, 丁安子, 等. 兼香型白酒贮存期挥发性成分变化规律[J]. 食品科学, 2014, 35(24): 115-118.
HUANG Q, CHEN M B, DING Z A, et al. Changing patterns of volatile flavor components of miscellaneous-type Chinese liquor during storage[J]. Food Science, 2014, 35(24): 115-118.
[20] WU Y S, HOU Y X, CHEN H, et al. "Key factor" for Baijiu quality: Research progress on acid substances in Baijiu[J]. Foods, 2022, 11(19): 2 959.
[21] 陈彦和, 孙细珍, 熊亚青, 等. 清香型白酒陶坛贮藏过程中挥发性物质变化分析[J]. 食品与发酵工业, 2023, 49(17): 94-103.
CHEN Y H, SUN X Z, XIONG Y Q, et al. Analysis of the changes of important aroma compounds in light-flavor Baijiu during pithos storage[J]. Food and Fermentation Industries, 2023, 49(17): 94-103.
[22] ZHANG W X, WU Z Y, ZHANG Q S, et al. Combination of newly developed high quality Fuqu with traditional Daqu for Luzhou-flavor liquor brewing[J]. World Journal of Microbiology and Biotechnology, 2009, 25(10): 1 721-1 726.
[23] JIANG J, LIU Y C, LI H H, et al. Modeling and regulation of higher alcohol production through the combined effects of the C/N ratio and microbial interaction[J]. Journal of Agricultural and Food Chemistry, 2019, 67(38): 10 694-10 701.
[24] 任宏彬. 汾酒香气成分及陈酿行为的研究[D]. 太原: 山西大学, 2016: 38-43.
REN H B. Research on Fenjiu aroma components and aging behaviors[D]. Taiyuan: Shanxi University, 2016: 38-43.
[25] FAN W L, XU Y, QIAN M. Current practice and future trends of aroma and flavor research in Chinese Baijiu[M]// Sex, smoke, and spirits: The role of chemistry. [S.l.]: American Chemical Society, 2019: 145-175.
[26] 代金凤, 罗政, 文春平, 等. 不同贮藏环境对浓香型白酒品质的影响[J]. 中国酿造, 2019, 38(5): 23-26.
DAI J F, LUO Z, WEN C P, et al. Effects of different storage environment on the quality of strong-flavor Baijiu[J]. China Brewing, 2019, 38(5): 23-26.