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Corresponding Author(s)

王瑾(1978—),女,浙江省产品质量安全科学研究院高级工程师,硕士。E-mail:wjin_920@163.com

Abstract

[Objective ] This study focus on exploring the factors affecting the migration of 14 heavy metal elements such as Ag,As and Pb in tableware and the migration patterns of each element.[Methods ] Silver tableware was chosen as an example,and the following parameters were chosen:silver purities (92.50%,99.00%,99.90%,99.99%),food simulants (drinking water,10% ethanol,5 g/L citric acid,4% acetic acid,tea),soaking temperatures (20,40,70 ℃),and soaking times (0.5,1.0,6.0,12.0,24.0 h),to design mixed level orthogonal experiments and perform data analysis using range and analysis of variance methods.[Results] All 14 heavy metal elements were detected,and with the increase of silver purity,the migration amount of Ag element also increased.When the food simulant was acidic or in the presence of ethanol,the migration of various elements in food simulants was relatively high,and with the increase of soaking time and soaking temperature,the migration of each element showed a certain increasing trend.[Conclusion ] When silver tableware products are exposed to acidic or alcoholic foods for a long time,the migration of heavy metal elements is relatively high,posing significant safety hazards.

Publication Date

2-18-2025

First Page

76

Last Page

83

DOI

10.13652/j.spjx.1003.5788.2023.81248

References

[1] EHSAN H,ATTAOLLAH S,MAHMOOD A,et al.Melamine migration measurement through spectrophotometry device and the effect of time and tableware type on it [J].Interdisciplinary Toxicology,2019,12(4):163-168.
[2] LIU S J,WANG Y F,LIU Z R,et al.Migration of melamine and its derivatives from melamine/bamboo/wheat straw -made tableware purchased from internet markets or retail shops in China [J].Toxics,2024,12(2):143.
[3] 童嘉琦,詹何珊,朱晓艳,等.一次性塑料餐具中风险物质的筛查 [J].分析测试学报,2022,41(10):1 523-1 529.TONG J Q,ZHAN H S,ZHU X Y,et al.Screening of specified risk materials in disposable plastic tableware [J].Journal of Instrumental Analysis,2022,41(10):1 523-1 529.
[4] 李宁,肖海清,王宏伟,等.不同塑料餐具中典型毒害物质的暴露评估 [J].现代食品科技,2022,38(9):321-332.LI N,XIAO H Q,WANG H W,et al.Exposure assessment of typical toxic substances in different plastic tableware sets [J].Modern Food Science and Technology,2022,38(9):321-332.
[5] 符灵梅,王玉健,徐莉.HPLC法同时测定食品接触橡胶密封垫圈中 3种醛类化合物迁移量 [J].食品与机械,2022,38(1):78-82.FU L M,WANG Y J,XU L.Simultaneous determination on migration of three aldehydes in food contact rubber gaskets by HPLC [J].Food & Machinery,2022,38(1):78-82.
[6] 袁悦,赵方蕾,杨道远,等.我国食品接触用不锈钢制品中金属元素迁移理论风险评估 [J].中国食品卫生杂志,2023,35(5):712-716.YUAN Y,ZHAO F L,YANG D Y,et al.Theoretical risk assessment of metal elements from stainless -steel products for food contact in China [J].Chinese Journal of Food Hygiene,2023,35(5):712-716.
[7] LIU W,WANG X L,ZHONG H N,et al.Risk assessment of eighteen elements leaching from ceramic tableware in China [J].Food Additives & Contaminants Part B -Surveillance,2023,16|(3):209-218.
[8] SZYNAL T,REBENIAK M,MANIA M.Migration studies of nickel and chromium from ceramic and glass tableware into food simulants [J].Roczniki Panstwowego Zakladu Higieny,2016,67(3):247-252.
[9] 资英娟,李岩,黎烽,等.银离子对几种细菌的杀菌效应 [J].水产学报,2020,44(9):1 457-1 466.ZI Y J,LI Y,LI F,et al.Mechanism underlying prolonged antibacterial effect of silver ion [J].Journal of Fisheries of China,2020,44(9):1 457-1 466.
[10] 那勃,刘琳,孟建华.银餐具中银迁移量的影响因素研究 [J].贵金属,2021,42(4):61-65.NA B,LIU L,MENG J H.Research on the influence factors of silver migration in silver tableware [J].Precious Metals,2021,42(4):61-65.
[11] 任悦,马军,宁娜静,等.银制餐具中重金属迁移安全风险及使用安全性研究 [J].现代食品,2021 (5):169-171.REN Y,MA J,NING N J,et al.Study on safety risk and use safety of heavy metal migration in silver tableware [J].Modern Food,2021 (5):169-171.
[12] 郝莉花,任悦,赵丽娜,等.食品接触用银制品中 8种重金属元素迁移量研究 [J].包装工程,2021,42(3):136-142.HAO L H,REN Y,ZHAO L N,et al.Migration of 8 heavy metal elements in silver products for food contact [J].Packaging Engineering,2021,42(3):136-142.
[13] 那勃.银餐具中砷、镉、铅迁移量的测定 [J].中国标准化,2020 (4):205-207.NA B.Determination of arsenic,cadmium and lead migration in silver tableware tableware [J].China Standardization,2020(4):205-207.
[14] GHO H,YUN H C,LEE J Y,et al.Monitoring of heavy metals,bisphenol A and phenol migrated from food packages for delivery [J].Analytical Science and Technology,2022,35(1):15-23.
[15] MERTOGLUELMAS G,CINAR G.Toxic metals in paper and paperboard food packagings [J].Bioresources,2018,13(4):7 560-7 580.
[16] ALTUNDAG H,YILDIRIM E,ALTINTIG E.Determination of some heavy metals by ICP -OES in edible parts of fish from Sapanca Lake and streams [J].Journal of Chemical Metrology,2019,13(1):7-13.
[17] 周健南.四类锅具在模拟酸性食品烹饪条件下的重金属元素迁移规律研究 [D].沈阳:沈阳农业大学,2022:11-14.ZHOU J N.Study on four types of pots in the migration law of heavy metal elements under simulated acid food cooking conditions [D].Shenyang:Shenyang Agricultural University,2022:11-14.
[18] 魏东,郭贺影.金属食品接触材料中 5种重金属元素的迁移量检测分析 [J].现代食品,2022,28(3):160-162.WEI D,GUO H Y.Detection and analysis of migration of five heavy metal elements in metal food contact materials [J].Modern Food,2022,28(3):160-162.
[19] 中华人民共和国国家卫生和计划生育委员会.食品安全国家标准 食品接触材料及制品砷、镉、铬、铅的测定和砷、镉、铬、镍、铅、锑、锌迁移量的测定:GB 31604.49—2016 [S].北京:中国标准出版社,2016.National Health and Family Planning Commission of the People's Republic of China.National food safety standard:Determination of arsenic,cadmium,chromium,and lead in food contact materials and products,and determination of arsenic,cadmium,chromium,nickel,lead,antimony,and zinc migration:GB 31604.49—2016 [S].Beijing:China Standard Press,2016.
[20] 国家市场监督管理总局,国家标准化管理委员会.生活饮用水标准检验方法 第6部分:金属和类金属指标:GB/T 5750.6—2023 [S].北京:中国标准出版社,2023.State Administration for Market Regulation,Standardization Administration.Standard examination methods for drinking water:metal parameters:GB/T 5750.6—2023 [S].Beijing:China Standards Press,2023.
[21] 滕海英,祝国强,黄平,等.正交试验设计实例分析 [J].药学服务与研究,2008 (1):75-76.TENG H Y,ZHU G Q,HUANG P,et al.Example analysis of orthogonal experimental design [J].Pharmaceutical Care and Research,2008 (1):75-76.

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